Pine tannin-based rigid foams: Mechanical and thermal properties

被引:101
作者
Lacoste, C. [1 ]
Basso, M. C. [1 ,2 ]
Pizzi, A. [1 ]
Laborie, M-P [3 ]
Celzard, A. [4 ]
Fierro, V. [4 ]
机构
[1] Univ Lorraine, LERMAB, Epinal, France
[2] SILVA Chim, INDUNOR, Buenos Aires, DF, Argentina
[3] Univ Freiburg, Inst Forest Utilizat & Works Sci, D-79106 Freiburg, Germany
[4] Univ Lorraine, IJL, Epinal, France
关键词
Pine tannin; Rigid foams; Mechanical performance; Thermal conductivity; Formulation; Resins; PROCESSING PARAMETERS;
D O I
10.1016/j.indcrop.2012.07.039
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Pine bark tannin foams were prepared for the first time. The high reactivity of pine tannins in relation to other tannins induced the change in the tannin foam formulations in order to coordinate foam resin hardening, reaction exotherm and solvent blowing allowing the formation of a rigid foam. Pine tannin foams with and without formaldehyde were prepared. Their characteristics were tested as regards stress-strain curves, thermal conductivity, Young's modulus, compression strength, densification, densification rate and energy absorbed under compression. Mostly, properties the pine tannin foams with formaldehyde have properties similar to mimosa tannin foams, in some cases slightly lower and in others slightly higher. Pine tannin foams without formaldehyde showed lower mechanical strength and more elastic behaviour. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:245 / 250
页数:6
相关论文
共 15 条
[1]   Flammability properties and mechanical performance of epoxy modified phenolic foams [J].
Auad, Maria L. ;
Zhao, Lihua ;
Shen, Hongbin ;
Nutt, Steven R. ;
Sorathia, Usman .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (03) :1399-1407
[2]  
Basso M.C., 2011, French patent application, Patent No. [11/025821, 11025821]
[3]   Mechanical properties of tannin-based rigid foams undergoing compression [J].
Celzard, A. ;
Zhao, W. ;
Pizzi, A. ;
Fierro, V. .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2010, 527 (16-17) :4438-4446
[4]  
Gibson L. J., 1997, CELLULAR SOLIDS STRU, V2nd ed
[5]   ACID-CATALYZED AND ALKALI-CATALYZED TANNIN-BASED RIGID FOAMS [J].
MEIKLEHAM, NE ;
PIZZI, A .
JOURNAL OF APPLIED POLYMER SCIENCE, 1994, 53 (11) :1547-1556
[6]  
Pizzi A., 2003, HDB ADHESIVE TECHNOL, V2
[7]  
Pizzi A., 1998, NATURAL TANNIN BASED
[8]   INCREASED PINE TANNINS EXTRACTION AND WOOD ADHESIVES DEVELOPMENT BY PHLOBAPHENES MINIMIZATION [J].
SEALYFISHER, VJ ;
PIZZI, A .
HOLZ ALS ROH-UND WERKSTOFF, 1992, 50 (05) :212-220
[9]   Mechanical characterization of short fiber reinforced phenolic foam [J].
Shen, HB ;
Nutt, S .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2003, 34 (09) :899-906
[10]  
Tondi G, 2008, MADERAS-CIENC TECNOL, V10, P219