Covalent Organic Frameworks for Water Treatment

被引:116
作者
Xia, Zijing [1 ,2 ,3 ,4 ]
Zhao, Yusen [5 ]
Darling, Seth B. [1 ,2 ,3 ,4 ]
机构
[1] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
[2] Argonne Natl Lab, Ctr Mol Engn, Lemont, IL 60439 USA
[3] Argonne Natl Lab, Adv Mat Energy Water Syst, Energy Frontier Res Ctr, Lemont, IL 60439 USA
[4] Univ Chicago, Pritzker Sch Mol Engn, Chicago, IL 60637 USA
[5] Univ Calif Los Angeles, Dept Mat Sci & Engn, Henry Samueil Sch Engn & Appl Sci, Los Angeles, CA 90095 USA
关键词
filtration; membranes; organic frameworks; solar steam; sorption; water treatment; HEAVY-METAL IONS; AQUEOUS-SOLUTION; CARBON-DIOXIDE; WASTE-WATER; REMOVAL; MEMBRANES; ADSORPTION; EFFICIENT; CONSTRUCTION; PERFORMANCE;
D O I
10.1002/admi.202001507
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Covalent organic frameworks (COFs) are an emerging type of porous crystalline material with highly ordered aperture size and tunable structures with designer properties. COFs have been proposed as promising materials for water treatment because of their notable intrinsic properties like excellent chemostability, high surface area, abundant functional sites, and uniform adjustable aperture size. This review focuses on fundamental COF design principles for water treatment (stability, aperture size, and surface functionalization) and the state-of-the-art application of COFs in desalination, organic contaminant sorption, and ion capture. Additional potential promising applications of COFs for water treatment, including solar steam generation, photocatalysis for degradation of organic contaminants, and capacitive deionization are also presented along with an outlook toward future opportunities in the field.
引用
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页数:17
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