Studies on the BF3 • Et2O/MCM-41 solid acid catalyst and its catalytic performance

被引：0

作者：

Zhou, RX ^{[1
]}

Mo, LY

Zhao, SF

Wang, YJ

Zheng, XM

机构：

[1] Zhejiang Univ, Inst Catalysis, Hangzhou 310028, Peoples R China

[2] Zhejiang Normal Univ, Dept Chem, Jinhua 321004, Peoples R China

来源：

CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2001年 / 22卷 / 09期

关键词：

BF3 center dot Et2O/MCM-41; epichlorohydrin; isobutanol; condensation reaction; 1-isobutoxy-3-chloropropanol;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A solid acid catalyst has been prepared by grafting Boron trifluoride on mesoporous molecular sieve MCM-41 and characterized by XRD and FTIR techniques. The XRD and FTIR results indicated that the (BF3Et2O)-Et-. interlocks with the silicon groups of MCM-41 surface to form strong solid acid. The solid acid catalyst would effectively promote the opening of epichlorohydrin with isobutanol to form 1-isobutoxy-3-chloropropanol, and showed a nice activity and selectivity.

引用

页码：1576 / 1577

页数：2