Effect of Cu content on the reaction behaviors of self-propagating high-temperature synthesis in Cu-Ti-B4C system

被引:43
作者
Liang, Y. H.
Wang, H. Y.
Yang, Y. F.
Zhao, R. Y.
Jiang, Q. C. [1 ]
机构
[1] Jilin Univ, Key Lab Automobile Mat Minist Educ, Changchun 130025, Peoples R China
基金
中国国家自然科学基金;
关键词
self-propagating high-temperature synthesis (SHS); ceramic; Cu; reaction behavior;
D O I
10.1016/j.jallcom.2007.08.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The SHS reaction behaviors of the Cu-Ti-B4C System with various Cu content were investigated. Theoretical calculation of the adiabatic temperatures reveals that the reaction in the Cu-Ti-B4C system is self-sustainable for the presence of 0-72.22 wt.% Cu in the reactants without any preheat. With the increase of Cu content, the adiabatic temperatures, combustion temperatures and wave velocity decrease greatly, while the ignition time shows first a remarkable decrease and then an increase with the minimum value at 20 wt.% Cu. Moreover, with the increase of Cu content, the sizes of the TiC and TiB2 grains decrease considerably. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:113 / 118
页数:6
相关论文
共 25 条
[1]   A new approach to the modeling of SHS reactions: Combustion synthesis of transition metal aluminides [J].
Gennari, Silvia ;
Tamburini, Umberto Anselmi ;
Maglia, Filippo ;
Spinolo, Giorgio ;
Munir, Zuhair A. .
ACTA MATERIALIA, 2006, 54 (09) :2343-2351
[2]   Dense in situ TiB2/TiN and TiB2/TiC ceramic matrix composites:: reactive synthesis and properties [J].
Gotman, I ;
Travitzky, NA ;
Gutmanas, EY .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 1998, 244 (01) :127-137
[3]  
GUERRERO AH, 1992, COMBUST SCI TECHNOL, V81, P115
[4]   CONSOLIDATION OF COMBUSTION-SYNTHESIZED TITANIUM DIBORIDE-BASED MATERIALS [J].
HOKE, DA ;
MEYERS, MA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1995, 78 (02) :275-284
[5]   Innovative processing of porous and cellular materials by chemical reaction [J].
Kanetake, N ;
Kobashi, M .
SCRIPTA MATERIALIA, 2006, 54 (04) :521-525
[6]   In situ processing of TiB2/TiC ceramic composites by thermal explosion under pressure:: experimental study and modeling [J].
Klinger, L ;
Gotman, I ;
Horvitz, D .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2001, 302 (01) :92-99
[7]   Ignition phenomena and reaction mechanisms of the self-propagating high-temperature synthesis reaction in the titanium-carbon-aluminum system [J].
Lee, WC ;
Chung, SL .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1997, 80 (01) :53-61
[8]  
LIANG YH, INT J REFRA IN PRESS
[9]  
LIANG YJ, 1996, NOTEBOOK THERMODYNAM
[10]   COMBUSTION SYNTHESIS OF ADVANCED MATERIALS .1. REACTION PARAMETERS [J].
MOORE, JJ ;
FENG, HJ .
PROGRESS IN MATERIALS SCIENCE, 1995, 39 (4-5) :243-273