Synergistic Effects of Alkylated Graphene Oxide on the Properties of Polypropylene-Based Carbon Nanocomposites

被引:5
作者
Yun, Young Soo [1 ]
Pyo, Hye-Ri [1 ]
Lee, Jae Yun [1 ]
Chin, In-Joo [1 ]
Jin, Hyoung-Joon [1 ]
机构
[1] Inha Univ, Dept Polymer Sci & Engn, Inchon 402751, South Korea
基金
新加坡国家研究基金会;
关键词
Graphene Oxide; Carbon Black; Nanocomposite; Hybrid; Polypropylene; ENHANCED THERMAL-CONDUCTIVITY; ISOTACTIC POLYPROPYLENE; BLACK; COMPOSITES; FILLERS;
D O I
10.1166/jnn.2013.7865
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polypropylene (PP)/carbon black (CB)-alkylated graphene oxide (AGO) hybrid nanocomposites were prepared via solution process and the synergistic effects of AGO on the properties of the PP/CB nanocomposites were investigated. AGO at a content of only 0.2 wt% formed an overlapped network structure in the PP matrix and affected the electrical, thermal and mechanical properties of the PP/CB nanocomposites. Specifically, PP/CB (5 wt%)-AGO (0.2 wt%) nanocomposites exhibited an electrical percolation threshold at lower CB contents than the PP/CB nanocomposites did, and the sheet resistance was decreased to 2.3x10(7) Omega/sq. The thermal degradation temperature and recrystallization temperature of the PP/CB (10 wt%) nanocomposites were increased by 11.3 and 1.6 degrees C, respectively, by the addition of 0.2 wt% AGO. In addition, the Young's modulus of the PP/CB (10 wt%) nanocomposite was increased from 438.1 to 540.1 MPa.
引用
收藏
页码:7062 / 7066
页数:5
相关论文
共 15 条
[1]   Characterization and thermal degradation mechanism of isotactic polypropylene/carbon black nanocomposites [J].
Chrissafis, K. ;
Paraskevopoulos, K. M. ;
Stavrev, S. Y. ;
Docoslis, A. ;
Vassiliou, A. ;
Bikiaris, D. N. .
THERMOCHIMICA ACTA, 2007, 465 (1-2) :6-17
[2]   Graphene/Polymer Nanocomposites [J].
Kim, Hyunwoo ;
Abdala, Ahmed A. ;
Macosko, Christopher W. .
MACROMOLECULES, 2010, 43 (16) :6515-6530
[3]   Enhanced thermal conductivity of polymer composites filled with hybrid filler [J].
Lee, GW ;
Park, M ;
Kim, J ;
Lee, JI ;
Yoon, HG .
COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING, 2006, 37 (05) :727-734
[4]  
Li FK, 2000, J APPL POLYM SCI, V75, P68, DOI 10.1002/(SICI)1097-4628(20000103)75:1<68::AID-APP8>3.3.CO
[5]  
2-9
[6]   The influence of carbon black on properties of oriented polypropylene 3. Thermal degradation under applied stress [J].
Miraftab, M ;
Horrocks, AR ;
Mwila, J .
POLYMER DEGRADATION AND STABILITY, 2002, 78 (02) :225-235
[7]   Crystallization of isotactic polypropylene containing carbon black as a filler [J].
Mucha, M ;
Marszalek, J ;
Fidrych, A .
POLYMER, 2000, 41 (11) :4137-4142
[8]   Graphene-based polymer nanocomposites [J].
Potts, Jeffrey R. ;
Dreyer, Daniel R. ;
Bielawski, Christopher W. ;
Ruoff, Rodney S. .
POLYMER, 2011, 52 (01) :5-25
[9]   Graphene-based composite materials [J].
Stankovich, Sasha ;
Dikin, Dmitriy A. ;
Dommett, Geoffrey H. B. ;
Kohlhaas, Kevin M. ;
Zimney, Eric J. ;
Stach, Eric A. ;
Piner, Richard D. ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2006, 442 (7100) :282-286
[10]   Thermally conductive nylon 6,6 and polycarbonate based resins. I. Synergistic effects of carbon fillers [J].
Weber, EH ;
Clingerman, ML ;
King, JA .
JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (01) :112-122