Copper-Catalyzed Dimerization/Cyclization of Itaconates

被引：4
|
作者：
Li, Zhiqiang [1 ]
Li, Ruirui [1 ]
Jiang, Lan [1 ]
Li, Zhengning [1 ]
机构：
[1] Dalian Univ, Coll Environm & Chem Engn, Dalian 116622, Peoples R China
来源：
MOLECULES | 2015年 / 20卷 / 08期
关键词：
copper; catalysis; domino reaction; itaconate; dimerization; cyclopentanone; ASYMMETRIC CONJUGATE ADDITION; DIALKYLZINC REAGENTS; ACID DERIVATIVES; 1,4-ADDITION; KETONES; OLIGOMERIZATION; REDUCTION; ALDEHYDES; LACTONE; ENONES;
D O I：
10.3390/molecules200815023
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.
引用
收藏
页码：15023 / 15032
页数：10
相关论文
共 50 条
  • [21] Copper-Catalyzed Aerobic Oxidative Azo-Ene Cyclization
    Kim, Junsu
    Lee, Da Hye
    Kim, Jinho
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (20) : 4728 - 4733
  • [22] Copper-catalyzed cascade azidation-cyclization of tryptophols and tryptamines
    Zhang, Panpan
    Sun, Wangsheng
    Li, Guofeng
    Hong, Liang
    Wang, Rui
    CHEMICAL COMMUNICATIONS, 2015, 51 (61) : 12293 - 12296
  • [23] Copper-catalyzed synthesis of quinazolines via cascade cyclization/hydrodehalogenation
    Ma, Peng
    Wang, Yuhang
    Wang, Jianhui
    Ma, Ning
    NEW JOURNAL OF CHEMISTRY, 2023, 47 (19) : 9377 - 9382
  • [24] Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines
    Zhang, Hong-Yu
    Mao, Liu-Liang
    Yang, Bin
    Yang, Shang-Dong
    CHEMICAL COMMUNICATIONS, 2015, 51 (19) : 4101 - 4104
  • [25] Copper-Catalyzed Activation of Dioxygen: Oxidative Cyclization of 2-Arylindoles
    Sang, Peng
    Xie, Yongju
    Zou, Jianwei
    Zhang, Yuhong
    ADVANCED SYNTHESIS & CATALYSIS, 2012, 354 (10) : 1873 - 1878
  • [26] Copper-catalyzed carbochlorination or carbobromination via radical cyclization of aryl amines
    Ouyang, Jianing
    Su, Xiaolong
    Chen, Yu
    Yuan, Yaofeng
    Li, Yi
    TETRAHEDRON LETTERS, 2016, 57 (13) : 1438 - 1441
  • [27] Copper-catalyzed Tandem Cyclization to Access 4-Aminoquinoline Derivatives
    Sheng, Hui-Yang
    Chen, Hui
    Liao, Meng
    Peng, Na
    Yang, Mian
    Cai, Qun
    Liu, Yi
    CHEMISTRY LETTERS, 2020, 49 (05) : 526 - 529
  • [28] Copper-catalyzed Buchner reaction and phenyl cyclopropanation through diyne cyclization
    Li, Tong
    He, Jia-Juan
    Fan, Kai-Yu
    Ye, Long-Wu
    Zhou, Bo
    Zhu, Xin-Qi
    ORGANIC CHEMISTRY FRONTIERS, 2025, 12 (06): : 1966 - 1972
  • [29] Copper-catalyzed cyclization of iodo-tryptophans:: A straightforward synthesis of pyrroloindoles
    Coste, Alexis
    Toumi, Mathieu
    Wright, Karen
    Razafimahaleo, Vanessa
    Couty, Francois
    Marrot, Jerome
    Evano, Gwilherm
    ORGANIC LETTERS, 2008, 10 (17) : 3841 - 3844
  • [30] Attomole electrophoretic analysis of catecholamines using copper-catalyzed intramolecular cyclization
    Gostkowski, ML
    Wei, J
    Okerberg, E
    Shear, JB
    ANALYTICAL BIOCHEMISTRY, 2002, 303 (02) : 199 - 202
12345