Copper-Catalyzed Dimerization/Cyclization of Itaconates

被引：4
|
作者：
Li, Zhiqiang [1 ]
Li, Ruirui [1 ]
Jiang, Lan [1 ]
Li, Zhengning [1 ]
机构：
[1] Dalian Univ, Coll Environm & Chem Engn, Dalian 116622, Peoples R China
来源：
MOLECULES | 2015年 / 20卷 / 08期
关键词：
copper; catalysis; domino reaction; itaconate; dimerization; cyclopentanone; ASYMMETRIC CONJUGATE ADDITION; DIALKYLZINC REAGENTS; ACID DERIVATIVES; 1,4-ADDITION; KETONES; OLIGOMERIZATION; REDUCTION; ALDEHYDES; LACTONE; ENONES;
D O I：
10.3390/molecules200815023
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
A copper-catalyzed domino reaction between itaconate esters and diethyl zinc (or silane) is developed, affording itaconate dimerization products, multi-ester-substituted cyclopentanones, in moderate to high yields.
引用
收藏
页码：15023 / 15032
页数：10
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