Luminescence of Nanocrystalline Erbium-Doped Yttria

被引:124
作者
Mao, Yuanbing [1 ]
Tran, Thai [2 ]
Guo, Xia [3 ]
Huang, Jian Y. [4 ]
Shih, C. Ken [2 ]
Wang, Kang L. [3 ]
Chang, Jane P. [1 ]
机构
[1] Univ Calif Los Angeles, Dept Chem & Biomol Engn, Los Angeles, CA 90095 USA
[2] Univ Texas Austin, Dept Phys, Austin, TX 78712 USA
[3] Univ Calif Los Angeles, Dept Elect Engn, Los Angeles, CA 90095 USA
[4] Sandia Natl Labs, CINT, Albuquerque, NM 87185 USA
基金
美国国家科学基金会;
关键词
UP-CONVERSION LUMINESCENCE; CRYSTAL-FIELD ANALYSIS; EU-GD2O3; NANOPARTICLES; HYDROTHERMAL SYNTHESIS; RED EMISSION; Y2O3; BULK; ER3+; PHOTOLUMINESCENCE; SPECTROSCOPY;
D O I
10.1002/adfm.200800880
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper, the luminescence, including photoluminescence, upconversion and cathodoluminescence, from single-crystalline erbium-doped yttria nanoparticles with an average diameter of 80 nm, synthesized by a molten salt method, is reported. Outstanding luminescent properties, including sharp and well-resolved photoluminescent lines in the infrared region, outstanding green and red upconversion emissions, and excellent cathodoluminescence, are observed from the nanocrystalline erbium-doped yttria. Moreoaver, annealing by the high power laser results in a relatively large increase in photoluminescent emission intensity without causing spectral line shift. These desirable properties make these nanocrystals promising for applications in display, bioanalysis and telecommunications.
引用
收藏
页码:748 / 754
页数:7
相关论文
共 45 条
[1]  
[Anonymous], 2004, ENCY NANOSCIENCE NAN
[2]  
Blasse G., 1994, LUMINESCENT MAT, P1, DOI [10.1007/978-3-642-79017-1_1, DOI 10.1007/978-3-642-79017-1_1, 10.1007/978-3-642-79017-11, DOI 10.1007/978-3-642-79017-11]
[3]   Enhancement of red emission (4F9/2→4I15/2) via upconversion in bulk and nanocrystalline cubic Y2O3:Er3+ [J].
Capobianco, JA ;
Vetrone, F ;
Boyer, JC ;
Speghini, A ;
Bettinelli, M .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (06) :1181-1187
[4]   Optical spectroscopy of nanocrystalline cubic Y2O3:Er3+ obtained by combustion synthesis [J].
Capobianco, JA ;
Vetrone, F ;
D'Alesio, T ;
Tessari, G ;
Speghini, A ;
Bettinelli, M .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (14) :3203-3207
[5]   A comparison between different methods of calculating the radiative lifetime of the 4I13/2 level of Er3+ in various glasses [J].
Chen, BJ ;
Righini, GC ;
Bettinelli, M ;
Speghini, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2003, 322 (1-3) :319-323
[6]   Concentration dependence of visible up-conversion luminescence in the laser crystal Gd3Ga5O12 doped with erbium [J].
Chen, XS ;
Nguyen, T ;
Luu, Q ;
Di Bartolo, B .
JOURNAL OF LUMINESCENCE, 2000, 85 (04) :295-299
[7]   Crystal field analysis of erbium doped yttrium oxide thin films in C2 and C3i sites [J].
Dammak, M ;
Maalej, R ;
Kamoun, M ;
Deschanvres, JL .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 2003, 239 (01) :193-202
[8]   Upconversion luminescence properties of Y2O3:Yb3+, Er3+ nanostructures [J].
De, GH ;
Qin, WP ;
Zhang, JS ;
Zhang, JH ;
Wang, Y ;
Cao, CY ;
Cui, Y .
JOURNAL OF LUMINESCENCE, 2006, 119 :258-263
[9]   Application of luminescent Eu:Gd2O3 nanoparticles to the visualization of protein micropatterns -: art. no. 064006 [J].
Dosev, D ;
Nichkova, M ;
Liu, MZ ;
Guo, B ;
Liu, GY ;
Hammock, BD ;
Kennedy, IM .
JOURNAL OF BIOMEDICAL OPTICS, 2005, 10 (06)
[10]   Synthesis and characterization of nanophase yttria co-doped with erbium and ytterbium [J].
Eilers, H .
MATERIALS LETTERS, 2006, 60 (02) :214-217