On viscosity of selected normal and associated liquids

被引:4
|
作者
Prezhdo, Oleg [1 ]
Drogosz, Andrzej [2 ]
Zubkova, Valentina [3 ]
Prezhdo, Victor [3 ]
机构
[1] Univ Rochester, Dept Chem, Rochester, NY 14627 USA
[2] Jan Kochanowski Univ, Inst Phys, PL-25406 Kielce, Poland
[3] Jan Kochanowski Univ, Inst Chem, PL-25406 Kielce, Poland
关键词
Viscosity; Benzene derivatives; Ordinary liquids; Associated liquids; Hydrogen bond; CYCLOHEXANE; MOLECULES; DENSITY;
D O I
10.1016/j.molliq.2013.03.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The viscosity of 34 benzene derivatives was determined at 404, 445, and 457 K to establish the relationship between the macroscopic properties of ordinary liquids, in particular viscosity, and the properties of molecules these liquids consist of. The nature of changes in viscosity in homologous and isologous series of compounds along with substituted compounds was explained on the basis of this dependence. The peculiarities of viscosity of associated compounds were determined and explained by hydrogen bonding. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:32 / 38
页数:7
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