Cross Dehydrogenative Coupling (CDC) Reactions of N,N-Disubstituted Formamides, Benzaldehydes and Cycloalkanes

被引：44

作者：

Batra, Aanchal ^{[3
]}

Singh, Paramjit ^{[1
,2
]}

Singh, Kamal Nain ^{[1
,2
]}

机构：

[1] Panjab Univ, Dept Chem, Chandigarh 160014, India

[2] Panjab Univ, Ctr Adv Studies Chem, Chandigarh 160014, India

[3] DAV Coll, Dept Chem, Sec 10-D, Chandigarh, India

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 2016卷 / 29期

关键词：

C-H activation; C-C coupling; C-X coupling; Cross coupling; Dehydrogenation; Peroxides; Radical reactions; C-H BONDS; METAL-FREE CONDITIONS; CATALYZED OXIDATIVE AMIDATION; ALPHA-OXOCARBOXYLIC ACIDS; CARBON-HYDROGEN BONDS; DIRECT ACCESS; MILD CONDITIONS; NITROGEN ATOM; CONVENIENT SYNTHESIS; AROMATIC-ALDEHYDES;

D O I：

10.1002/ejoc.201600401

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In recent years, reactions of inexpensive and easily available formamides, benzaldehydes and cycloalkanes with various coupling partners have made an impact in the field of cross dehydrogenative coupling. Even in the absence of a benzylic C-H site or a heteroatom at the a-position, these substrates react efficiently under oxidative conditions. This review article highlights recent advances in cross dehydrogenative coupling reactions for C-C and C-heteroatom bond formation with the above substrates.

引用

页码：4927 / 4947

页数：21

共 118 条

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