Indirect synthesis of a pair of formal methane activation products at a phosphane/borane frustrated Lewis pair

被引：8
|
作者：
Froemel, Silke [1 ]
Daniliuc, Constantin G. [1 ]
Bannwarth, Christoph [2 ]
Grimme, Stefan [2 ]
Bussmann, Kathrin [1 ]
Kehr, Gerald [1 ]
Erker, Gerhard [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, Corrensstr 40, D-48149 Munster, Germany
[2] Univ Bonn, Inst Phys & Theoret Chem, Mulliken Ctr Theoret Chem, Beringstr 4, D-53115 Bonn, Germany
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 48期
关键词：
ZETA-VALENCE QUALITY; C-H BORYLATION; POLYMERIZATION CATALYSTS; OLEFIN POLYMERIZATION; NITRIC-OXIDE; BASIS-SETS; CHEMISTRY; REACTIVITY; COMPLEXES; HYDROGEN;
D O I：
10.1039/c6dt04206f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The regioisomeric formal Mes(2)PCH(2)CH(2)B(C6F5)(2) FLP methane splitting products Mes(2)P(H)CH2CH2B(CH3)(C6F5)(2) and Mes(2)P(CH3) CH2CH2B(H)(C6F5)(2) were produced by indirect stepwise reactions. They were stable at 60 degrees C and were both characterized by X-ray diffraction. A DFT analysis revealed that their formation from the FLP and CH4 would be endergonic by +6.9 and +3.6 kcal mol(-1), respectively, and it indicated that methane elimination from the zwitterionic products is kinetically hindered by barriers of 54.0 and 72.3 kcal mol(-1), respectively.
引用
收藏
页码：19230 / 19233
页数：4
相关论文
共 50 条
  • [31] Frustrated Lewis Pair Chelation in the p-Block
    Frenette, Brandon L.
    Rivard, Eric
    CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (65)
  • [32] Enamine/butadienylborane cycloaddition in the frustrated Lewis pair regime
    Chen, Guo-Qiang
    Tuerkyilmaz, Fatma
    Daniliuc, Constantin G.
    Bannwarth, Christoph
    Grimme, Stefan
    Kehr, Gerald
    Erker, Gerhard
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2015, 13 (42) : 10477 - 10486
  • [33] Dehydrogenation of amine-boranes with a frustrated Lewis pair
    Miller, Alexander J. M.
    Bercaw, John E.
    CHEMICAL COMMUNICATIONS, 2010, 46 (10) : 1709 - 1711
  • [34] "Frustrated Lewis pair" hydrogenations
    Stephan, Douglas W.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (30) : 5740 - 5746
  • [35] Aggregation Behavior of a Six-Membered Cyclic Frustrated Phosphane/Borane Lewis Pair: Formation of a Supramolecular Cyclooctameric Macrocyclic Ring System
    Jie, Xiaoming
    Daniliuc, Constantin G.
    Knitsch, Robert
    Hansen, Michael Ryan
    Eckert, Hellmut
    Ehlert, Sebastian
    Grimme, Stefan
    Kehr, Gerald
    Erker, Gerhard
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (03) : 882 - 886
  • [36] Catalytic Dehydrogenation of Ammonia Borane Mediated by a Pt(0)/Borane Frustrated Lewis Pair: Theoretical Design
    Zhang, Lei
    Oishi, Takumi
    Gao, Liuzhou
    Hu, Shiyu
    Yang, Linlin
    Li, Wei
    Wu, Shengjun
    Shang, Rong
    Yamamoto, Yohsuke
    Li, Shuhua
    Wang, Wei
    Zeng, Guxiang
    CHEMPHYSCHEM, 2020, 21 (23) : 2573 - 2578
  • [37] Novel H2 activation by a tris[3,5-bis(trifluoromethyl)phenyl]borane frustrated Lewis pair
    Herrington, Thomas J.
    Thom, Alex J. W.
    White, Andrew J. P.
    Ashley, Andrew E.
    DALTON TRANSACTIONS, 2012, 41 (30) : 9019 - 9022
  • [38] Design and reactions of a carbon Lewis base/boron Lewis acid frustrated Lewis pair
    Moericke, Jennifer
    Wibbeling, Birgit
    Daniliuc, Constantin G.
    Kehr, Gerald
    Erker, Gerhard
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2101):
  • [39] Frustrated Lewis Pair Route to Hydrodesilylation of Silylphosphines
    Takeuchi, Katsuhiko
    Hounjet, Lindsay J.
    Stephan, Douglas W.
    ORGANOMETALLICS, 2013, 32 (16) : 4469 - 4472
  • [40] Synthesis of an oxygen-linked germinal frustrated Lewis pair and its application in small molecule activation
    Wang, Yiheng
    Li, Zhen Hua
    Wang, Huadong
    RSC ADVANCES, 2018, 8 (46) : 26271 - 26276
12345