Conversion and kinetics study of fructose-to-5-hydroxymethylfurfural (HMF) using sulfonic and ionic liquid groups bi-functionalized mesoporous silica nanoparticles as recyclable solid catalysts in DMSO systems

被引：113

作者：

Lee, Yin-Ying ^{[1
]}

Wu, Kevin C. -W. ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem Engn, Taipei 10617, Taiwan

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2012年 / 14卷 / 40期

关键词：

DEHYDRATION; FRUCTOSE; ACID; MONOSACCHARIDES;

D O I：

10.1039/c2cp42751f

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mesoporous silica nanoparticles functionalized with both sulfonic acid (HSO3) and ionic liquid (ILs) were synthesized and applied as effective and recyclable catalysts for generating 5-hydroxymethylfurfural (HMF) from fructose. For the first time a high HMF yield of 72.5% was achieved in DMSO systems under mild conditions (90 degrees C and 3 h). We further studied the kinetics of the fructose-to-HMF conversion and compared the rate constants, reaction orders, and activation energies for the systems with and without bi-functional MSN catalysts.

引用

页码：13914 / 13917

页数：4

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