X-ray excited luminescence of Ga- and In-doped ZnO microrods by annealing treatment

被引:12
作者
Li, Qianli [1 ]
Liu, Xiaolin [1 ]
Gu, Mu [1 ]
Huang, Shiming [1 ]
Zhang, Juannan [1 ]
Ni, Chen [1 ]
Liu, Bo [1 ]
Hu, Yahua [1 ]
Wu, Qiang [1 ]
Zhao, Shuning [1 ]
机构
[1] Tongji Univ, Sch Phys Sci & Engn, Shanghai Key Lab Special Artificial Microstruct M, Shanghai 200092, Peoples R China
基金
中国国家自然科学基金;
关键词
Ga- and In-doped ZnO microrods; Hydrothermal process; Annealing treatment; X-ray excited luminescence; NANOSTRUCTURES; SCINTILLATOR; GROWTH;
D O I
10.1016/j.spmi.2016.09.005
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Ga- and In-doped ZnO microrods were prepared by low temperature hydrothermal process, and the effect of annealing temperature on morphology, crystallization, photoluminescence and X-ray excited luminescence were deeply researched. The results showed that both Ga- and In-doped ZnO microrods were possessed of a good crystalline quality and exhibited an intense visible emission band with a blue-shift under X-ray excitation. This blue-shift of the visible luminescence could be ascribed to the different contributions of the defect emissions, i.e. the increase in the oxygen vacancy (V-o) emission and the decrease of the oxygen interstitial (O-j) emission. Moreover, a strong ultraviolet luminescence was also obtained by further hydrogen annealing. It is expected that Ga- and In doped microrods are promising candidates for development of fast and high-spatial resolution X-ray imaging detectors. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码:351 / 358
页数:8
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