Ga- and In-doped ZnO microrods were prepared by low temperature hydrothermal process, and the effect of annealing temperature on morphology, crystallization, photoluminescence and X-ray excited luminescence were deeply researched. The results showed that both Ga- and In-doped ZnO microrods were possessed of a good crystalline quality and exhibited an intense visible emission band with a blue-shift under X-ray excitation. This blue-shift of the visible luminescence could be ascribed to the different contributions of the defect emissions, i.e. the increase in the oxygen vacancy (V-o) emission and the decrease of the oxygen interstitial (O-j) emission. Moreover, a strong ultraviolet luminescence was also obtained by further hydrogen annealing. It is expected that Ga- and In doped microrods are promising candidates for development of fast and high-spatial resolution X-ray imaging detectors. (C) 2016 Elsevier Ltd. All rights reserved.
机构:
Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Bourret-Courchesne, E. D.
;
Derenzo, S. E.
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Univ Calif Berkeley, Lawrence Berkeley Lab, Div Life Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Derenzo, S. E.
;
Weber, M. J.
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Univ Calif Berkeley, Lawrence Berkeley Lab, Div Life Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
机构:
Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Bourret-Courchesne, E. D.
;
Derenzo, S. E.
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h-index: 0
机构:
Univ Calif Berkeley, Lawrence Berkeley Lab, Div Life Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
Derenzo, S. E.
;
Weber, M. J.
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h-index: 0
机构:
Univ Calif Berkeley, Lawrence Berkeley Lab, Div Life Sci, Berkeley, CA 94720 USAUniv Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA