Regiospecific synthesis of symmetrical (1E,3E) 2,3-diphenyl-1,4diphenyl-buta-1,3-dienes via palladium-catalyzed cross-coupling of (Z) 2-bromo-2-fluoroethenylbenzenes in presence of bis(pinacolato)diboron

被引：10

作者：

Eddarir, S

Rolando, C

机构：

[1] Univ Sci & Technol, CNRS, UMR 8009, Equipe Polyphenols, F-59655 Villeneuve Dascq, France

[2] Univ Cadi Ayyad, Fac Sci Tech Gueliz, Marrakech, Morocco

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 03期

关键词：

regiospecific synthesis; fluorodiene; bromofluoroolefin; homo coupling; palladium; boron;

D O I：

10.1016/j.jfluchem.2003.08.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cross-coupling reaction of (Z) 1-bromo-1-fluoroalkenes catalyzed by PdCl2(PPh3)(2)-2PPh(3) (3%) and CsF in Tetrahydrofuran (THF) in presence of bis(pinacolato)diboron led to (1E,3E) 2,3-difluoro-1,4-disubstituted-buta-1,3-dienes in high yields. (C) 2003 Elsevier B.V. All rights reserved.

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收藏

页码：377 / 380

页数：4

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