(2,2'-bipyridyl-N,N')dibromopalladium(II)

被引：18
|
作者：
Smeets, WJJ
Spek, AL
Hoare, JL
Canty, AJ
Hovestad, N
vanKoten, G
机构：
[1] UNIV TASMANIA,DEPT CHEM,HOBART,TAS 7001,AUSTRALIA
[2] UNIV UTRECHT,DEBYE INST,DEPT MET MEDIATED SYNTH,NL-3584 CH UTRECHT,NETHERLANDS
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S0108270197004149
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title complex, [PdBr2(C10H8N2)], has square-planar geometry for palladium with Pd-N 2.047(5) and PdBr 2.4102(9)Angstrom. The mean planes of the coordinated pyridine groups form a dihedral angle of 1.7(3)degrees with the coordination square plane; the parallel complexes stack with an interplanar spacing of 3.41(1)Angstrom and a Pd...Pd separation of 5.246(1)A to form a chain structure as reported for isomorphous PtI2(bipy) (where bipy is 2,2'-bipyridyl, C10H8N2). The structure differs from those found for related chain structures in the 'red' form of PtCl2(bipy) and in PdCl2(bipy) which is isomorphous with the 'yellow' form of PtCl2(bipy).
引用
收藏
页码：1045 / 1047
页数：3
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