"Click" Bis-Triazoles as Neutral C-H•••Anion-Acceptor Organocatalysts

被引：40
作者：
Beckendorf, Stephan [1 ]
Asmus, Soeren [1 ]
Mueck-Lichtenfeld, Christian [1 ]
Mancheno, Olga Garcia [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 05期
关键词：
alkylation; anion acceptor; click chemistry; NMR spectroscopy; organocatalysis; triazoles; 1,3-DIPOLAR CYCLOADDITIONS; POLYMER; CHEMISTRY; CATALYSIS; EFFICIENT; CHLORIDE; LIGATION; MICHAEL; LIGANDS; BINDING;
D O I：
10.1002/chem.201203360
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new player on the field! "Click" bis-triazoles have been introduced as a highly efficient new class of neutral C-H⋯anion-binding organocatalysts (see scheme). DFT and NMR studies were used to confirm this activation modus and identify the optimal catalyst. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：1581 / 1585
页数：5
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