Catalytic epoxidation of styrene by molecular oxygen over a novel catalyst of copper hydroxyphosphate Cu2(OH)PO4

被引:30
作者
Meng, XJ
Sun, ZH
Wang, RW
Lin, S
Sun, JM
Yang, M
Lin, KF
Jiang, DZ
Xiao, FS [1 ]
机构
[1] Jilin Univ, Dept Chem, Changchun 130023, Peoples R China
[2] Jilin Univ, Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
基金
中国国家自然科学基金;
关键词
styrene epoxidation; molecular oxygen; copper hydroxyphosphate;
D O I
10.1023/A:1016755404975
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Catalytic epoxidation of styrene by molecular oxygen over a novel copper hydroxyphosphate catalyst, Cu-2(OH)PO4, was studied. Catalytic data show that the catalyst Cu-2(OH)PO4 is very active, and the main products are benzaldehyde and styrene epoxide. Some important factors associated with the catalytic activity and selectivity have been investigated extensively.
引用
收藏
页码:105 / 109
页数:5
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