Double-armed calix[4]arene amide derivatives as ionophores for lead ion-selective electrodes

被引：57

作者：

Chen, LX ^{[1
]}

Zhang, J ^{[1
]}

Zhao, WF ^{[1
]}

He, XW ^{[1
]}

Liu, Y ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, State Key Lab Funct Polymer Mat Adsorpt & Separat, Tianjin 300071, Peoples R China

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2006年 / 589卷 / 01期

基金：

中国国家自然科学基金;

关键词：

lead; ion-selective electrode; calix[4]arene derivatives;

D O I：

10.1016/j.jelechem.2006.02.001

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A number of double-armed calix[4]arene amide derivatives (1-7) have been tested as the neutral ionophores for lead ion-selective electrodes. The electrodes based on ionophores 1-7 except 5, 6 with dioctyl phthalate (DOP) as a plasticizer exhibit a close theoretical Nernstian response for Pb2+ over a relatively wide concentration range (1 x 10(-6)-1 x 10(-1) M), a fast response time (< 15 s), at least two months lifetime and good selectivity towards alkali, alkaline earth and some common transition metal ions. (c) 2006 Elsevier B.V. All rights reserved.

引用

收藏

页码：106 / 111

页数：6

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