Investigation on the Adsorption and Corrosion Inhibition Behavior of Gum Acacia and Synergistic Surfactants Additives on Mild Steel in 0.1M H2SO4

被引:35
作者
Mobin, M. [1 ]
Khan, M. Alam [1 ]
机构
[1] Aligarh Muslim Univ, Dept Appl Chem, Corros Res Lab, Aligarh 202002, Uttar Pradesh, India
关键词
Adsorption isotherm; corrosion inhibition; gum acacia; mild steel; surfactant; synergistic effect; NONIONIC SURFACTANTS; ACID; ALUMINUM; IRON; PROTECTION; IMPEDANCE; IODIDE; MEDIA; IONS;
D O I
10.1080/01932691.2012.751031
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Adsorption and corrosion inhibition effect of gum acacia alone and in presence of surfactants sodium dodecyl benzene sulphonate and cetyltrimethyl ammonium bromide on mild steel in 0.1M H2SO4 in temperature range of 30 to 60 degrees C was investigated using weight loss method, chemical analysis of solution, scanning electron microscopy, atomic force microscopy and determination of thermodynamic parameters. Inhibiting action of gum acacia is synergistically enhanced on addition of small amount of surfactants. SEM and AFM results confirmed the existence of an adsorbed protective film on the mild steel surface. Thermodynamic parameters reveal that adsorption process is spontaneous and obey Freundlich adsorption isotherm.
引用
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页码:1496 / 1506
页数:11
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