Syntheses, structures, and reactivities of borylcopper and -zinc compounds:: 1,4-silaboration of an α,β-unsaturated ketone to form a γ-siloxyallylborane

被引：154

作者：

Kajiwara, Takashi ^{[1
]}

Terabayashi, Tomomi ^{[1
]}

Yamashita, Makoto ^{[1
]}

Nozaki, Kyoko ^{[1
]}

机构：

[1] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Bunkyo Ku, Tokyo 1138656, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 35期

关键词：

allylic compounds; anions; boron; copper; zinc;

D O I：

10.1002/anie.200801728

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) New borylcopper and borylzinc compounds were synthesized by transmetalation of boryllithium with metal halides. The 1,4-addition of lithium borylbromocuprate [BCu(μ2-Br)Li(thf) 3] to 2-cyclohexen-1-one as a boryl anion, followed by trapping of the resulting boron-substituted copper enolate with Me3SiCl, afforded the γ-siloxyallylborane. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：6606 / 6610

页数：5

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