Synthesis of dimethyl ether from methane mediated by HBr

被引：16

作者：

You, Qin ^{[1
]}

Liu, Zhen ^{[1
]}

Li, Wensheng ^{[1
]}

Zhou, Xiaoping ^{[1
,2
]}

机构：

[1] Hunan Univ, Dept Chem Engn, Changsha 410082, Hunan, Peoples R China

[2] Nanjing Univ Technol, Coll Life Sci & Pharmaceut Engn, Nanjing 210009, Jiangsu, Peoples R China

来源：

JOURNAL OF NATURAL GAS CHEMISTRY | 2009年 / 18卷 / 03期

基金：

芬兰科学院;

关键词：

dimethyl ether; methane oxidative bromination; methyl bromide; catalyst; HYBRID CATALYSTS; SYNTHESIS GAS; SOLID-ACID; DEHYDRATION; SYNGAS; CONVERSION; PERFORMANCE; DME;

D O I：

10.1016/S1003-9953(08)60122-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Dimethyl ether (DME) was synthesized from methane through a two-step process, in which CH3Br was prepared from the oxidative bromination reaction of methane in the presence of HBr and oxygen over a Rh-SiO2 catalyst and then, in the second step, CH3Br was hydrolyzed to DME over a silica supported metal chloride catalyst. 12 mol%ZnCl2/SiO2 catalyst was found to be the most active, but it deactivated because of Cl- losing.

引用

页码：306 / 311

页数：6

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