β-Diiminato ligand (L) transformations in reactions of KL with PI3 and I2 [L={N(C6H3Pri2-2,6)C(H)}2CPh]

被引：11

作者：

Hitchcock, Peter B. ^{[1
]}

Lappert, Michael F. ^{[1
]}

Li, Gang ^{[1
]}

Protchenko, Andrey V. ^{[1
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 08期

关键词：

D O I：

10.1039/b611260a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the potassium beta-diiminate KL (L=[{N(Ar)-C(H)}(2)CPh](-); Ar=C6H3Pr2i-2,6) with PI3 unexpectedly produced a phosphenium salt of the intermolecularly C, C-coupled ligand [P(I){N(Ar)CH}(2)C(C6H4-4)C(Ph)-(CH=NAr)(2)](+)[I-3](-), while an intramolecularly N, N-coupled salt [N(Ar)C(H)C(Ph)C(H)N(Ar)](+)[I-5](-) was isolated from KL + I-2.

引用

页码：846 / 848

页数：3

共 21 条

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