Luminescence of an Oxonitridoberyllate: A Study of Narrow-Band Cyan-Emitting Sr[Be6ON4]:Eu2+

被引:86
作者
Strobel, Philipp [1 ]
de Boer, Tristan [2 ]
Weiler, Volker [3 ]
Schmidt, Peter J. [3 ]
Moewes, Alexander [2 ]
Schnick, Wolfgang [1 ]
机构
[1] Univ Munich LMU, Dept Chem, Butenandtstr 5-13, D-81377 Munich, Germany
[2] Univ Saskatchewan, Dept Phys & Engn Phys, 116 Sci Pl, Saskatoon, SK S7N 5E2, Canada
[3] Lumileds Germany GmbH, Lumileds Phosphor Ctr Aachen, Philipsstr 8, D-52068 Aachen, Germany
基金
加拿大自然科学与工程研究理事会; 加拿大健康研究院;
关键词
CRYSTAL-STRUCTURE; ELECTRONIC-STRUCTURE; BERYLLIUM; PHOSPHOR; SRSI2O2N2EU2+; SPECTRA;
D O I
10.1021/acs.chemmater.8b01256
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Oxo- and (oxo)nitridoberyllates show exceptional potential as host lattices for application in illumination grade phosphor converted (pc)LEDs due to their remarkable electronic and structural characteristics, allowing highly efficient narrow-band emission upon doping with Eu2+. Sr[Be6ON4]:Eu2+, the first example of an oxonitridoberyllate phosphor, exhibits narrow-band cyan emission (lambda(em) = 495 nm; full width at half-maximum, fwhm = 35 nm; approximate to 1400 cm(-1)), comparable to the emission of the oxonitridosilicate BaSi2O2N2:Eu2+ (fwhm = 35 nm) or a cyan-emitting primary LED (fwhm = 27 nm). Sr[Be6ON4]:Eu2+ reveals a highly condensed rigid 3D network with a remarkably large degree of condensation [i.e., atomic ratio Be:(O,N)] of kappa = 1.2 that is achieved by interconnection of highly condensed layers of BeN4 tetrahedra by Be2ON6 units via common edges. The crystal structure of Sr[Be6ON4]:Eu2+ was solved on the basis of single-crystal and powder XRD data (C2/c, no. 15, a = 13.9283(14), b = 5.7582(6), c = 4.9908(5) angstrom, beta = 90.195(1)degrees, Z = 4, R-1 = 0.033, wR(2) = 0.065, GoF = 1.046). Sr[Be6ON4]:Eu2+ shows a close structural relationship to other nitride as well as oxide compounds, and therefore closes a structural gap helping to understand relations in Be-containing solid-state materials. The electronic structure of Sr[Be6ON4]:Eu2+ was characterized by X-ray spectroscopy measurements, supported by density functional theory (DFT) calculations. Due to its excellent emission properties, large band gap, rigid 3D network, as well as chemical and thermal stability, Sr[Be6ON4]:Eu2+ is a promising phosphor to close the cyan gap in efficient high-CRI pcLEDs (CRI, color rendering index).
引用
收藏
页码:3122 / 3130
页数:9
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