Silicon- and Tin-Based Cuprates: Now Catalytic in Copper!

被引：66
作者：
Weickgenannt, Andreas [1 ]
Oestreich, Martin [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 02期
关键词：
allylic substitution; catalysis; conjugate addition; copper; main group elements; zinc; ALPHA; BETA-UNSATURATED CARBONYL-COMPOUNDS; SIMPLE MONOSILYLCOPPER REAGENT; CONJUGATE SILYL TRANSFER; ALPHA-BETA-UNSATURATION; STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; ORGANIC-SYNTHESIS; DIASTEREOSELECTIVE SYNTHESIS; BIS(TRIORGANOSILYL) ZINCS; STEREOSPECIFIC SYNTHESIS;
D O I：
10.1002/chem.200902222
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Silicon- and tin-containing molecules are versatile building blocks in organic synthesis. A stalwart method for their preparation relies on the stoichiometric use of silicon- and tin-based cuprates, although a few copper(I)-catalyzed or even copper-free protocols have been known for decades. In this Concept, we describe our efforts towards copper(l)-catalyzed carbon-silicon and also carbon-tin bond formations using soft bis-(triorganosilyl) and bis(triorganostannyl) zinc reagents as powerful sources of nucleophilic silicon and tin. Conjugate addition, allylic substitution, and carbon-carbon multiple bond functionalization is now catalytic in copper!
引用
收藏
页码：402 / 412
页数：11
相关论文
共 50 条
[21]   New Pyrazole-Based Ligands: Synthesis, Characterization, and Catalytic Activity of Their Copper Complexes [J].
Nadia Bouroumane ;
Mohamed El Kodadi ;
Rachid Touzani ;
Mohamed El Boutaybi ;
Adyl Oussaid ;
Belkheir Hammouti ;
Asep Bayu Dani Nandiyanto .
Arabian Journal for Science and Engineering, 2022, 47 :269-279
[22]   New Pyrazole-Based Ligands: Synthesis, Characterization, and Catalytic Activity of Their Copper Complexes [J].
Bouroumane, Nadia ;
El Kodadi, Mohamed ;
Touzani, Rachid ;
El Boutaybi, Mohamed ;
Oussaid, Adyl ;
Hammouti, Belkheir ;
Nandiyanto, Asep Bayu Dani .
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2022, 47 (01) :269-279
[23]   Mesoporous silica based copper catalytic materials for potential deNOx application: Synthesis and characterization [J].
Deze, Evangelia G. ;
Bareka, Maria D. ;
Karousos, Dionysis S. ;
Sapalidis, Andreas A. ;
Favvas, Evangelos P. .
INTERNATIONAL CONFERENCES & EXHIBITION ON NANOTECHNOLOGIES, ORGANIC ELECTRONICS & NANOMEDICINE, NANOTEXNOLOGY 2020, PT 1, 2021, 54 :1-6
[24]   Mesoporous silica based copper catalytic materials for potential deNOx application: Synthesis and characterization [J].
Deze, Evangelia G. ;
Bareka, Maria D. ;
Karousos, Dionysis S. ;
Sapalidis, Andreas A. ;
Favvas, Evangelos P. .
MATERIALS TODAY-PROCEEDINGS, 2022, 54 :1-6
[25]   Copper-based catalysts for water gas shift reaction: Influence of support on their catalytic activity [J].
Pradhan, S. ;
Reddy, A. Satyanarayana ;
Devi, R. N. ;
Chilukuri, Satyanarayana .
CATALYSIS TODAY, 2009, 141 (1-2) :72-76
[26]   Recent advances in copper-based materials for robust lithium polysulfides adsorption and catalytic conversion [J].
Liang, Fengxing ;
Zhu, Yongzheng ;
Wang, Nannan ;
Zhu, Meiping ;
He, Huibing ;
Zhu, Yanqiu ;
Shen, Peikang ;
Zhu, Jinliang .
CHINESE CHEMICAL LETTERS, 2024, 35 (11)
[27]   Catalytic Activity and Performance of Copper-Based Complexes Mediating Atom Transfer Radical Polymerization [J].
Tsarevsky, Nicolay V. .
ISRAEL JOURNAL OF CHEMISTRY, 2012, 52 (3-4) :276-287
[28]   A new catalytic approach for aerobic oxidation of primary alcohols based on a Copper(I)-thiophene carbaldimines [J].
Lagerspets, Emi ;
Valbonetti, Evelyn ;
Eronen, Aleksi ;
Repo, Timo .
MOLECULAR CATALYSIS, 2021, 509
[29]   Enhancement of hydrodeoxygenation catalytic performance through the addition of copper to molybdenum oxide-based catalysts [J].
Dionizio, Debora G. B. ;
Forrer, Leticia ;
Berhault, Gilles ;
de Souza, Priscilla M. ;
Henriques, Cristiane A. .
MOLECULAR CATALYSIS, 2023, 536
[30]   Electronic structures and photovoltaic properties of copper- or tin-doped cesium-based perovskite crystals [J].
Enomoto, Ayu ;
Suzuki, Atsushi ;
Oku, Takeo ;
Fukunishi, Sakiko ;
Tachikawa, Tomoharu ;
Hasegawa, Tomoya .
OPEN CERAMICS, 2023, 16
12345