New insights into solvent-induced structural changes of 13C labelled metal-organic frameworks by solid state NMR

被引：16

作者：

Rauche, Marcus ^{[1
]}

Ehrling, Sebastian ^{[2
]}

Krause, Simon ^{[2
,3
]}

Senkovska, Irena ^{[2
]}

Kaskel, Stefan ^{[2
]}

Brunner, Eike ^{[1
]}

机构：

[1] Tech Univ Dresden, Chair Bioanalyt Chem, D-01062 Dresden, Germany

[2] Tech Univ Dresden, Chair Inorgan Chem 1, D-01062 Dresden, Germany

[3] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 62期

关键词：

CO2; CAPTURE; SPECTROSCOPY; TRANSITIONS; DUT-8(NI); PRESSURE; DYNAMICS; CENTERS; SPECTRA; MOFS; NI;

D O I：

10.1039/c9cc04298a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective C-13-labelling of carboxylate carbons in the linker molecules of flexible metal-organic frameworks (MOFs) makes solid-state NMR spectroscopy very powerful to investigate solvent-induced local structural changes as demonstrated by C-13 and H-1 NMR spectroscopy on the pillared layer MOF DUT-8(Ni). Selective identification of polar solvent-node interactions becomes feasible.

引用

页码：9140 / 9143

页数：4

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