New insights into solvent-induced structural changes of 13C labelled metal-organic frameworks by solid state NMR

被引：16
|
作者：
Rauche, Marcus [1 ]
Ehrling, Sebastian [2 ]
Krause, Simon [2 ,3 ]
Senkovska, Irena [2 ]
Kaskel, Stefan [2 ]
Brunner, Eike [1 ]
机构：
[1] Tech Univ Dresden, Chair Bioanalyt Chem, D-01062 Dresden, Germany
[2] Tech Univ Dresden, Chair Inorgan Chem 1, D-01062 Dresden, Germany
[3] Univ Groningen, Stratingh Inst Chem, NL-9747 AG Groningen, Netherlands
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 62期
关键词：
CO2; CAPTURE; SPECTROSCOPY; TRANSITIONS; DUT-8(NI); PRESSURE; DYNAMICS; CENTERS; SPECTRA; MOFS; NI;
D O I：
10.1039/c9cc04298a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selective C-13-labelling of carboxylate carbons in the linker molecules of flexible metal-organic frameworks (MOFs) makes solid-state NMR spectroscopy very powerful to investigate solvent-induced local structural changes as demonstrated by C-13 and H-1 NMR spectroscopy on the pillared layer MOF DUT-8(Ni). Selective identification of polar solvent-node interactions becomes feasible.
引用
收藏
页码：9140 / 9143
页数：4
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