Frustrated Lewis pair behavior of a neutral scandium complex

被引：27

作者：

Chang, Kejian ^{[1
]}

Xu, Xin ^{[1
]}

机构：

[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Key Lab Organ Synth Jiangsu Prov, Suzhou 215123, Peoples R China

来源：

DALTON TRANSACTIONS | 2017年 / 46卷 / 14期

基金：

中国国家自然科学基金;

关键词：

ZIRCONOCENE-PHOSPHINOARYLOXIDE COMPLEXES; LATE HETEROBIMETALLIC COMPLEXES; HETEROCYCLIC CARBENE COMPLEX; SMALL-MOLECULE ACTIVATION; FREE HYDROGEN ACTIVATION; CARBON-DIOXIDE; PHOSPHAZINE COMPLEXES; METAL; REACTIVITY; CATALYSIS;

D O I：

10.1039/c7dt00676d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An easily-accessible neutral scandium complex Sc[OC(CH3)(2)CH2PPh2] [O-2,6-tBu(2)-C6H3](2)[THF] behaves as a reactive Sc/P frustrated Lewis pair, which when added to organic and inorganic substrates e.g. carbonyl compounds, transition-metal chlorides, and diazoalkane compounds, yields unique and intriguing addition products such as a Sc/Rh heterobimetallic complex and a Sc phosphazine complex.

引用

页码：4514 / 4517

页数：4

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