Metal-bipyridine/phenanthroline-functionalized porous crystalline materials: Synthesis and catalysis

被引：33

作者：

Feng, Xiao ^{[1
]}

Ren, Yanwei ^{[1
]}

Jiang, Huanfeng ^{[1
]}

机构：

[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou, Guangdong, Peoples R China

来源：

COORDINATION CHEMISTRY REVIEWS | 2021年 / 438卷

关键词：

Metal-organic frameworks; Covalent organic frameworks; Metal-bipyridine complexes; Metal-phenanthroline complexes; Heterogeneous catalysis; COVALENT ORGANIC FRAMEWORK; PHOTOCATALYTIC HYDROGEN EVOLUTION; CARBON-DIOXIDE REDUCTION; HIGHLY EFFICIENT; WATER OXIDATION; CO2; REDUCTION; ELECTROCATALYTIC REDUCTION; PHOTOREDOX CATALYSIS; ELECTRON-TRANSFER; BIPYRIDINE;

D O I：

10.1016/j.ccr.2021.213907

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bipyridine(bpy)/phenanthroline(phen)-based ligands have been utilized widely to coordinate metals for homogeneous organic catalysis. The immobilization of M(bpy)/M(phen) active sites into porous supports is an intriguing approach to combine the appealing activities of homogeneous catalysts with the heterogeneity of the host materials. Herein we review the recent research progress of M(bpy)/M(phen)-functionalized metal-organic frameworks (MOFs) and covalent organic frameworks (COFs). Emphasis is focused on the synthetic strategies of these porous materials, as well as their catalytic performances in thermocatalysis, photocatalysis and electrocatalysis. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：23

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