Synthesis of 1,10-decanediol diacetate and 1-decanol acetate from furfural

被引：6

作者：

Deng, Chen-Qiang ^{[1
]}

Jiang, Qin-Zhu ^{[1
]}

Deng, Jin ^{[1
]}

Fu, Yao ^{[1
]}

机构：

[1] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, CAS Key Lab Urban Pollutant Convers, IChEM,Anhui Prov Key Lab Biomass Clean Energy,Dep, Hefei 230026, Anhui, Peoples R China

来源：

GREEN CHEMISTRY | 2021年 / 23卷 / 05期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

Condensation reactions - Furfural - Aldehydes;

D O I：

10.1039/d1gc00227a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A green and efficient method was developed for upgrading furfural to 1,10-decanediol diacetate and 1-decanol acetate. 92% yield of the acetates was obtained through the tandem benzoin condensation and hydrodeoxygenation reaction. During the benzoin condensation, furfural was catalyzed into furoin in a quantitative yield by the immobilized NHC catalyst under solvent-free conditions. After dissolving the furoin intermediate in acetic acid, the Sc(OTf)(3) and Pd/C catalytic system was introduced for hydrodeoxygenation. The effects of reaction factors have been investigated in detail and the hydrodeoxygenation process has been explored by H-1-NMR and GC-MS.

引用

页码：2169 / 2176

页数：8

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