2D Early Transition Metal Carbides (MXenes) for Catalysis

被引：313

作者：

Li, Zhe ^{[1
]}

Wu, Yue ^{[1
]}

机构：

[1] Iowa State Univ, Dept Chem & Biol Engn, Ames, IA 50011 USA

来源：

SMALL | 2019年 / 15卷 / 29期

关键词：

2D materials; electrocatalysis; MXenes; photocatalysis; thermal catalysis; HYDROGEN-PRODUCTION; DEHYDROGENATION; COMPOSITES; CONVERSION; NANOSHEETS; GRAPHENE; NITRIDE;

D O I：

10.1002/smll.201804736

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

MXenes, a bourgeoning class of 2D transition metal carbides, are of considerable interest in catalysis due to their rich surface chemistry, tunable electronic structures, and thermal stability. Here, recent conceptual advances in applying MXenes and their nanocomposites in (photo)electrocatalysis and conventional heterogeneous catalysis are highlighted. In addition, the nature of active sites in the MXene-based catalysts are discussed and the significance and challenges in the future development of catalysts using MXenes as the platforms are summarized.

引用

页数：10

共 45 条

[1] 2D metal carbides and nitrides (MXenes) for energy storage [J].

Anasori, Babak ;

Lukatskaya, Maria R. ;

Gogotsi, Yury .

NATURE REVIEWS MATERIALS, 2017, 2 (02)

[2]

[Anonymous], 2004, Enriching the earth: Fritz Haber, Carl Bosch, and the transformation of world food production

[3] Promising prospects for 2D d2-d4 M3C2 transition metal carbides (MXenes) in N2 capture and conversion into ammonia [J].

Azofra, Luis Miguel ;

Li, Neng ;

MacFarlane, Douglas R. ;

Sun, Chenghua .

ENERGY & ENVIRONMENTAL SCIENCE, 2016, 9 (08) :2545-2549

[4] 2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction [J].

Cao, Shaowen ;

Shen, Baojia ;

Tong, Tong ;

Fu, Junwei ;

Yu, Jiaguo .

ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (21)

[5] LITHIUM-AIR BATTERIES Something from nothing [J].

Cheng, Fangyi ;

Chen, Jun .

NATURE CHEMISTRY, 2012, 4 (12) :962-963

[6]

Chhowalla M, 2013, NAT CHEM, V5, P263, DOI [10.1038/NCHEM.1589, 10.1038/nchem.1589]

[7]

Deng DH, 2016, NAT NANOTECHNOL, V11, P218, DOI [10.1038/NNANO.2015.340, 10.1038/nnano.2015.340]

[8] Ti3C2Tx MXene Catalyzed Ethylbenzene Dehydrogenation: Active Sites and Mechanism Exploration from both Experimental and Theoretical Aspects [J].

Diao, Jiangyong ;

Hu, Minmin ;

Lian, Zan ;

Li, Zhaojin ;

Zhang, Hui ;

Huang, Fei ;

Li, Bo ;

Wang, Xiaohui ;

Su, Dang Sheng ;

Liu, Hongyang .

ACS CATALYSIS, 2018, 8 (11) :10051-10057

[9] Self-Assemble and In Situ Formation of Ni1-xFexPS3 Nanomosaic-Decorated MXene Hybrids for Overall Water Splitting [J].

Du, Cheng-Feng ;

Khang Ngoc Dinh ;

Liang, Qinghua ;

Zheng, Yun ;

Luo, Yubo ;

Zhang, Jianli ;

Yan, Qingyu .

ADVANCED ENERGY MATERIALS, 2018, 8 (26)

[10] How a century of ammonia synthesis changed the world [J].

Erisman, Jan Willem ;

Sutton, Mark A. ;

Galloway, James ;

Klimont, Zbigniew ;

Winiwarter, Wilfried .

NATURE GEOSCIENCE, 2008, 1 (10) :636-639

← 1 2 3 4 5 →