Selective hydrogenation of fatty acids and methyl esters of fatty acids to obtain fatty alcohols-a review

被引：76

作者：

Sanchez, Maria A. ^{[1
]}

Torres, Gerardo C. ^{[1
]}

Mazzieri, Vanina A. ^{[1
]}

Pieck, Carlos L. ^{[1
]}

机构：

[1] UNL, FIQ, CONICET, Inst Invest Catalisis & Petroquim INCAPE, Colectora Ruta Nac 168,Km 0, RA-3000 Paraje El Pozo, Santa Fe, Argentina

来源：

JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY | 2017年 / 92卷 / 01期

关键词：

selective hydrogenation; fatty alcohols; methyl esters; catalysts; COBALT-TIN CATALYSTS; SURFACE ORGANOMETALLIC CHEMISTRY; LIQUID-PHASE HYDROGENATION; SUPPORTED RU-SN; CITRAL HYDROGENATION; OLEIC-ACID; RUTHENIUM CATALYSTS; ALPHA; BETA-UNSATURATED ALDEHYDES; REDUCTION TEMPERATURE; CARBOXYLIC-ACIDS;

D O I：

10.1002/jctb.5039

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

In this paper, a review is presented of the evolution of different catalytic systems and operating conditions used in the selective hydrogenation of acids and esters of fatty acids to obtain fatty alcohols, which have broad industrial applications in the oleochemical industry. In addition, the current status of the different technologies used industrially (Lurgi, Davy and Henkel) for obtaining fatty alcohols, as well as major global sources of raw materials for the oleochemical industry are put forward. Finally, the reaction mechanisms of the selective hydrogenation process of oleic acid and methyl oleate to obtain the corresponding unsaturated alcohol as well as the new catalysts proposed by researchers are described. (C) 2016 Society of Chemical Industry

引用

页码：27 / 42

页数：16

共 146 条

[1]

Adkins H, 1964, ORG REACTIONS, V8, P1

[2]

Adkins H., 1931, J. Am. Chem. Soc., V53, P1095, DOI 10.1021/ja01354a042

[3]

Aguirre AD, 2002, APPL CATAL A-GEN, V233, P183

[4]

Ahmad W.R. a. S., 2006, Palm Oil Developments, P15