One-step nanocasting synthesis of sulfur and nitrogen co-doped ordered mesoporous carbons as efficient electrocatalysts for oxygen reduction

被引：13
作者：
Song, Xiaozeng [1 ]
Ren, Hongxin [1 ]
Ding, Junjie [1 ]
Wang, Chenfei [1 ]
Yin, Xin [1 ]
Wang, Haiwen [1 ]
机构：
[1] E China Univ Sci & Technol, Sch Chem & Mol Engn, Shanghai 200237, Peoples R China
来源：
MATERIALS LETTERS | 2015年 / 159卷
基金：
中国国家自然科学基金;
关键词：
Carbon materials; Porous materials; Oxygen reduction reaction; Fuel cell; METAL-FREE ELECTROCATALYSTS; CATALYSTS; GRAPHENE; BORON;
D O I：
10.1016/j.matlet.2015.06.112
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Ordered mesoporous carbon co-doped with sulfur and nitrogen (SN-OMC) is synthesized via one-step nanocasting route. Diphenylthiocarbazone is used as a single precursor for carbon, sulfur and nitrogen in the preparation of SN-OMCs. These catalysts are subjected to the physicochemical characterization and electrochemical evaluation toward the oxygen reduction reaction (ORR) in an alkaline electrolyte. SN-OMC obtained at 900 degrees C exhibits a high electrocatalytic activity for ORR and the impressive durability and methanol-tolerance. The synergistic effect of nitrogen and sulfur in mesoporous carbon walls may contribute to high oxygen electroreduction performance of SN-OMC. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：280 / 283
页数：4
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共 18 条
  • [1] SnO2-Au hybrid nanoparticles as effective catalysts for oxygen electroreduction in alkaline media
    Chen, Wei
    Ny, David
    Chen, Shaowei
    [J]. JOURNAL OF POWER SOURCES, 2010, 195 (02) : 412 - 418
  • [2] Ordered Mesoporous SBA-15 Type Graphitic Carbon Nitride: A Semiconductor Host Structure for Photocatalytic Hydrogen Evolution with Visible Light
    Chen, Xiufang
    Jun, Young-Si
    Takanabe, Kazuhiro
    Maeda, Kazuhiko
    Domen, Kazunari
    Fu, Xianzhi
    Antonietti, Markus
    Wang, Xinchen
    [J]. CHEMISTRY OF MATERIALS, 2009, 21 (18) : 4093 - 4095
  • [3] Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction
    Cheon, Jae Yeong
    Kim, Taeyoung
    Choi, YongMan
    Jeong, Hu Young
    Kim, Min Gyu
    Sa, Young Jin
    Kim, Jaesik
    Lee, Zonghoon
    Yang, Tae-Hyun
    Kwon, Kyungjung
    Terasaki, Osamu
    Park, Gu-Gon
    Adzic, Radoslav R.
    Joo, Sang Hoon
    [J]. SCIENTIFIC REPORTS, 2013, 3
  • [4] One-pot synthesis of nitrogen and sulfur co-doped onion-like mesoporous carbon vesicle as an efficient metal-free catalyst for oxygen reduction reaction in alkaline solution
    Han, Ce
    Bo, Xiangjie
    Zhang, Yufan
    Li, Mian
    Guo, Liping
    [J]. JOURNAL OF POWER SOURCES, 2014, 272 : 267 - 276
  • [5] Phosphorus-Doped Graphite Layers with High Electrocatalytic Activity for the O2 Reduction in an Alkaline Medium
    Liu, Zi-Wu
    Peng, Feng
    Wang, Hong-Juan
    Yu, Hao
    Zheng, Wen-Xu
    Yang, Jian
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (14) : 3257 - 3261
  • [6] Graphene-based non-noble-metal Co/N/C catalyst for oxygen reduction reaction in alkaline solution
    Niu, Kexing
    Yang, Baoping
    Cui, Jinfeng
    Jin, Jutao
    Fu, Xiaogang
    Zhao, Qiuping
    Zhang, Junyan
    [J]. JOURNAL OF POWER SOURCES, 2013, 243 : 65 - 71
  • [7] Fluorine-Doped Carbon Blacks: Highly Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction
    Sun, Xiujuan
    Zhang, Yuwei
    Song, Ping
    Pan, Jing
    Zhuang, Lin
    Xu, Weilin
    Xing, Wei
    [J]. ACS CATALYSIS, 2013, 3 (08): : 1726 - 1729
  • [8] Synthesis and Electrochemical Property of Boron-Doped Mesoporous Carbon in Supercapacitor
    Wang, Da-Wei
    Li, Feng
    Chen, Zhi-Gang
    Lu, Gao Qing
    Cheng, Hui-Ming
    [J]. CHEMISTRY OF MATERIALS, 2008, 20 (22) : 7195 - 7200
  • [9] Vertically Aligned BCN Nanotubes as Efficient Metal-Free Electrocatalysts for the Oxygen Reduction Reaction: A Synergetic Effect by Co-Doping with Boron and Nitrogen
    Wang, Shuangyin
    Iyyamperumal, Eswaramoorthi
    Roy, Ajit
    Xue, Yuhua
    Yu, Dingshan
    Dai, Liming
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (49) : 11756 - 11760
  • [10] Ammonia-Treated Ordered Mesoporous Carbons as Catalytic Materials for Oxygen Reduction Reaction
    Wang, Xiqing
    Lee, Je Seung
    Zhu, Qing
    Liu, Jun
    Wang, Yong
    Dai, Sheng
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (07) : 2178 - 2180
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