Thiolate Complexes Catalyst in Noble-Metal-Free System for Light-driven Hydrogen Production

被引：0

作者：

Li, Guang-Yan ^{[1
]}

Fu, Da-Tian ^{[2
]}

Cai, Xiu-Lan ^{[1
]}

机构：

[1] Guangdong Pharmaceut Univ, Guangzhou, Guangdong, Peoples R China

[2] Hainan Canc Hosp, Haikou, Hainan, Peoples R China

来源：

PROCEEDINGS OF THE 4TH 2016 INTERNATIONAL CONFERENCE ON MATERIAL SCIENCE AND ENGINEERING (ICMSE 2016) | 2016年 / 101卷

关键词：

Fe thiolate complexes; Photocatalysis; Hydrogen; VISIBLE-LIGHT; WATER; REDUCTION; EFFICIENT; ENERGY; SOLAR;

D O I：

暂无

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

In this paper, Fe thiolate complexes Fe(phen(pyS)(2) (M) were synthesized and the properties of complexes were characterized by H-1-NMR and MS. The effects of reaction conditions on performanceof Fe thiolate complexes Fe(phen(pyS)(2)had been studied. The results of catalytic performance implied thatwhen 2.0 mMfluorescein was used as photosensitizer, ethanol/water was used as solvent and its volume ratio of ethanol/water was 1:1, catalyst M showed the highest catalytic performance and hydrogen production was 115.6 mu mol/h after reacted for 15 h.

引用

页码：25 / 29

页数：5

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