Efficient and recyclable copper-based MOF-catalyzed N-arylation of N-containing heterocycles with aryliodides

被引：36

作者：

Li, Zihao ^{[1
]}

Meng, Fei ^{[2
]}

Zhang, Jie ^{[1
]}

Xie, Jianwei ^{[1
]}

Dai, Bin ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832003, Peoples R China

[2] Guangdong Acad Sci, Guangdong Bioengn Inst, Guangzhou 510316, Guangdong, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 46期

关键词：

ORGANIC FRAMEWORK MOF-199; CROSS-COUPLING REACTIONS; C-N; ARYLBORONIC ACIDS; ARYL HALIDES; HETEROGENEOUS CATALYST; NITROGEN-HETEROCYCLES; SUPPORTED COPPER(I); HIGHLY EFFICIENT; BOND FORMATION;

D O I：

10.1039/c6ob02068b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper-based MOF-199 was used as an efficient heterogeneous catalyst to catalyze cross-coupling reactions between N-containing heterocycles and aryliodides with high yields. The catalyst can be easily separated from the reaction mixture, and can be reused at least 5 times without significantly decreasing the activity. The XRD results showed that the crystallinity and structure of MOF-199 can be maintained well during the coupling reaction.

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页码：10861 / 10865

页数：5

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