B-H activation and H-H formation: two consecutive heterolytic processes on an osmium-hydrogensulfide bond

被引：22

作者：

Esteruelas, Miguel A. ^{[1
]}

Lopez, Ana M. ^{[1
]}

Mora, Malka ^{[1
]}

Onate, Enrique ^{[1
]}

机构：

[1] Univ Zaragoza, CSIC, ISQCH, Dept Quim Inorgan, E-50009 Zaragoza, Spain

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 68期

关键词：

TRANSITION-METAL-BORYL; AMMONIA-BORANE; CRYSTAL-STRUCTURE; C-H; COMPLEXES; REACTIVITY; DERIVATIVES; RUTHENIUM; LIGANDS; BORON;

D O I：

10.1039/c3cc44102d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Heterolytic B-H activation and H-H formation on an Os-SH bond give borylthiolate-dihydrogen derivatives. These species exchange borylthiol by borane to afford sigma-borane derivatives or release H-2 and undergo a hydride-boryl exchange to yield boryl-hydrogensulfide complexes depending on the boryl group bonded to the sulfur atom.

引用

页码：7543 / 7545

页数：3

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