Vanadium-catalyzed deoxydehydration of glycols

被引：85

作者：

Chapman, Garry, Jr. ^{[1
]}

Nicholas, Kenneth M. ^{[1
]}

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期

基金：

美国国家科学基金会;

关键词：

STATE PROPERTIES; SULFITE-DRIVEN; BIOMASS; CONVERSION; DIOLS; DEOXYGENATION; DERIVATIVES; MECHANISM; ALCOHOLS; ALKENES;

D O I：

10.1039/c3cc44656e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A survey of several metavandate (VO3-) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(v)-dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenyl-phosphine or sodium sulfite as reductants.

引用

页码：8199 / 8201

页数：3

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