Vanadium-catalyzed deoxydehydration of glycols

被引：85

作者：

Chapman, Garry, Jr. ^{[1
]}

Nicholas, Kenneth M. ^{[1
]}

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 74期

基金：

美国国家科学基金会;

关键词：

STATE PROPERTIES; SULFITE-DRIVEN; BIOMASS; CONVERSION; DIOLS; DEOXYGENATION; DERIVATIVES; MECHANISM; ALCOHOLS; ALKENES;

D O I：

10.1039/c3cc44656e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A survey of several metavandate (VO3-) and chelated dioxovanadium derivatives shows that tetrabutylammonium dioxovanadium(v)-dipicolinate most effectively catalyzes the deoxydehydration (DODH) of glycols to olefins in moderate to excellent yields with triphenyl-phosphine or sodium sulfite as reductants.

引用

页码：8199 / 8201

页数：3

共 32 条

[1] Sulfite-Driven, Oxorhenium-Catalyzed Deoxydehydration of Glycols [J].

Ahmad, Irshad ;

Chapman, Garry ;

Nicholas, Kenneth M. .

ORGANOMETALLICS, 2011, 30 (10) :2810-2818

[2] Catalytic conversion of biomass to biofuels [J].

Alonso, David Martin ;

Bond, Jesse Q. ;

Dumesic, James A. .

GREEN CHEMISTRY, 2010, 12 (09) :1493-1513

[3] Rhenium-Catalyzed Didehydroxylation of Vicinal Dials to Alkenes Using a Simple Alcohol as a Reducing Agent [J].

Arceo, Elena ;

Ellman, Jonathan A. ;

Bergman, Robert G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (33) :11408-11409

[4] Mechanism of the MeReO3-Catalyzed Deoxygenation of Epoxides [J].

Bi, Siwei ;

Wang, Jiayong ;

Liu, Lingjun ;

Li, Ping ;

Lin, Zhenyang .

ORGANOMETALLICS, 2012, 31 (17) :6139-6147

[5] Catalytic Deoxydehydration of Glycols with Alcohol Reductants [J].

Boucher-Jacobs, Camille ;

Nicholas, Kenneth M. .

CHEMSUSCHEM, 2013, 6 (04) :597-599

[6] Transformations of biomass-derived platform molecules: from high added-value chemicals to fuels via aqueous-phase processing [J].

Carlos Serrano-Ruiz, Juan ;

Luque, Rafael ;

Sepulveda-Escribano, Antonio .

CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) :5266-5281

[7] Toward nonoxidative routes to oxygenated organics: Stereospecific deoxydehydration of diols and polyols to alkenes and allylic alcohols catalyzed by the metal oxo complex (C(5)Me(5))ReO3 [J].

Cook, GK ;

Andrews, MA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (39) :9448-9449

[8] OXOVANADIUM(V) ALKOXIDE DERIVATIVES OF 1,2-DIOLS - SYNTHESIS AND SOLID-STATE V-51 NMR CHARACTERIZATION [J].

CRANS, DC ;

FELTY, RA ;

CHEN, HJ ;

ECKERT, H ;

DAS, N .

INORGANIC CHEMISTRY, 1994, 33 (11) :2427-2438

[9] Vanadium(IV) and vanadium(V) complexes of dipicolinic acid and derivatives. Synthesis, X-ray structure, solution state properties and effects in rats with STZ-induced diabetes [J].

Crans, DC ;

Mahroof-Tahir, M ;

Johnson, MD ;

Wilkins, PC ;

Yang, LQ ;

Robbins, K ;

Johnson, A ;

Alfano, JA ;

Godzala, ME ;

Austin, LT ;

Willsky, GR .

INORGANICA CHIMICA ACTA, 2003, 356 :365-378

[10]

Gable KP, 2006, ACS SYM SER, V921, P143

← 1 2 3 4 →