Palladium nanoparticles supported on a poly(N-vinyl-2-pyrrolidone)-modified mesoporous carbon nanocage as a novel heterogeneous catalyst for the Heck reaction in water

被引:23
作者
Kalbasi, Roozbeh Javad [1 ]
Nlosaddegh, Neda [1 ]
Abbaspourrad, Alireza [2 ]
机构
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 31186145, Isfahan, Iran
[2] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
关键词
Heck reaction; Mesoporous carbon nanocage; Pd nanoparticles; Water; LIGAND-FREE PALLADIUM; ARYL CHLORIDES; EFFICIENT; NANOCOMPOSITE; PRECURSORS; POLYMER; SYSTEM; SUZUKI;
D O I
10.1016/j.tetlet.2012.05.046
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Palladium nanoparticles supported on poly(N-vinyl-2-pyrrolidone)/CKT-3 (a mesoporous carbon nano-cage) were employed effectively as novel heterogeneous catalyst for the Heck coupling reaction. The results showed that aryl halides (-Cl, -Br, -I) underwent coupling with a variety of alkenes at 60 degrees C in water under aerobic conditions. The very stable nanocomposite catalyst was easily recovered, showed negligible Pd leaching, and retained good activity for at least ten successive runs without any additional activation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3763 / 3766
页数:4
相关论文
共 50 条
[41]   Palladium supported on a novel ordered mesoporous polypyrrole/carbon nanocomposite as a powerful heterogeneous catalyst for the aerobic oxidation of alcohols to carboxylic acids and ketones on water [J].
Ganji, Nasim ;
Karimi, Babak ;
Najafvand-Derikvandi, Sepideh ;
Vali, Hojatollah .
RSC ADVANCES, 2020, 10 (23) :13616-13631
[42]   Ru nanoparticles stabilized by poly(N-vinyl-2-pyrrolidone) grafted onto silica: Very active and stable catalysts for hydrogenation of aromatics [J].
Zhou, Xiaosi ;
Wu, Tianbin ;
Hu, Baoji ;
Jiang, Tao ;
Han, Buxing .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 306 (1-2) :143-148
[43]   Synthesis and characterization of poly(N-vinyl-2-pyrrolidone)-stabilized water-soluble nickel(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohydride [J].
Metin, Onder ;
Ozkar, Saim .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 295 (1-2) :39-46
[44]   Synthesis and characterization of Pd-poly(N-vinyl-2-pyrrolidone)/KIT-5 nanocomposite as a polymer-inorganic hybrid catalyst for the Suzuki-Miyaura cross-coupling reaction [J].
Kalbasi, Roozbeh Javad ;
Mosaddegh, Neda .
JOURNAL OF SOLID STATE CHEMISTRY, 2011, 184 (11) :3095-3103
[45]   Palladium nanoparticles supported on modified crosslinked polyacrylamide containing phosphinite ligand: A novel and efficient heterogeneous catalyst for carbon-carbon cross-coupling reactions [J].
Tamami, Bahman ;
Ghasemi, Soheila .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 322 (1-2) :98-105
[46]   Modified mesoporous graphitic carbon nitride: a novel high-performance heterogeneous base catalyst for transesterification reaction [J].
Devi, Meghali ;
Barbhuiya, Monjur H. ;
Das, Bishal ;
Bhuyan, Bishal ;
Dhar, Siddhartha S. .
SUSTAINABLE ENERGY & FUELS, 2020, 4 (07) :3537-3545
[47]   Palladium nanoparticles embedded on mesoporous TiO2 material (Pd@MTiO2) as an efficient heterogeneous catalyst for Suzuki-Coupling reactions in water medium [J].
Mondal, Paramita ;
Bhanja, Piyali ;
Khatunar, Resmin ;
Bhaumik, Asim ;
Das, Debasis ;
Islam, Sk. Manirul .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2017, 508 :378-386
[48]   Palladium Nanoparticles Supported on Poly(2-hydroxyethyl methacrylate)/KIT-6 Composite as an Efficient and Reusable Catalyst for Suzuki-Miyaura Reaction in Water [J].
Kalbasi, Roozbeh Javad ;
Mosaddegh, Neda .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2012, 22 (02) :404-414
[49]   Hydrogen generation from hydrolysis of ammonia borane in the presence of highly efficient poly(N-vinyl-2-pyrrolidone)-protected platinum-ruthenium nanoparticles [J].
Rakap, Murat .
APPLIED CATALYSIS A-GENERAL, 2014, 478 :15-20
[50]   N-Doped porous carbon supported palladium nanoparticles as a highly efficient and recyclable catalyst for the Suzuki coupling reaction [J].
Zhang, Li ;
Dong, Wen-Huan ;
Shang, Ning-Zhao ;
Feng, Cheng ;
Gao, Shu-Tao ;
Wang, Chun .
CHINESE CHEMICAL LETTERS, 2016, 27 (01) :149-154