Palladium nanoparticles supported on a poly(N-vinyl-2-pyrrolidone)-modified mesoporous carbon nanocage as a novel heterogeneous catalyst for the Heck reaction in water

被引：23
作者：
Kalbasi, Roozbeh Javad [1 ]
Nlosaddegh, Neda [1 ]
Abbaspourrad, Alireza [2 ]
机构：
[1] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 31186145, Isfahan, Iran
[2] Harvard Univ, Sch Engn & Appl Sci, Cambridge, MA 02138 USA
来源：
TETRAHEDRON LETTERS | 2012年 / 53卷 / 29期
关键词：
Heck reaction; Mesoporous carbon nanocage; Pd nanoparticles; Water; LIGAND-FREE PALLADIUM; ARYL CHLORIDES; EFFICIENT; NANOCOMPOSITE; PRECURSORS; POLYMER; SYSTEM; SUZUKI;
D O I：
10.1016/j.tetlet.2012.05.046
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium nanoparticles supported on poly(N-vinyl-2-pyrrolidone)/CKT-3 (a mesoporous carbon nano-cage) were employed effectively as novel heterogeneous catalyst for the Heck coupling reaction. The results showed that aryl halides (-Cl, -Br, -I) underwent coupling with a variety of alkenes at 60 degrees C in water under aerobic conditions. The very stable nanocomposite catalyst was easily recovered, showed negligible Pd leaching, and retained good activity for at least ten successive runs without any additional activation. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3763 / 3766
页数：4
相关论文
共 50 条
[31]   Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane [J].
Umegaki, Tetsuo ;
Yan, Jun-Min ;
Zhang, Xin-Bo ;
Shioyama, Hiroshi ;
Kuriyama, Nobuhiro ;
Xu, Qiang .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (09) :3816-3822
[32]   Palladium nanoparticles supported on poly (N-vinylpyrrolidone)-grafted silica as new recyclable catalyst for Heck cross-coupling reactions [J].
Tamami, Bahman ;
Allahyari, Hamed ;
Ghasemi, Soheila ;
Farjadian, Fatemeh .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (02) :594-599
[33]   PCP-pincer palladium nanoparticles supported on modified Merrifield resin: A novel and efficient heterogeneous catalyst for carbon-carbon cross-coupling reactions [J].
Tamami, Bahman ;
Nezhad, Molki Mohaghegh ;
Ghasemi, Soheila ;
Farjadian, Fatemeh .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2013, 743 :10-16
[34]   Poly (methyl methacrylate)-graphene oxide supported palladium catalyst: A ligand free protocol for Suzuki and Heck coupling reaction in water medium [J].
Basak, Puja ;
Ghosh, Pranab .
SYNTHETIC COMMUNICATIONS, 2018, 48 (19) :2584-2599
[35]   Facile preparation of palladium catalyst supported on silica nanoparticles through CS2 plasma pretreatment: Application to the Heck reaction for vinyl monomers and π-conjugated polymer synthesis [J].
Martha Jimenez-Barrera, Rosa ;
Gomez-Benitez, Valente ;
Guadalupe Neira-Velazquez, Maria ;
Roman Torres-Lubian, Jose ;
Moggio, Ivana ;
Arias, Eduardo ;
Chan-Navarro, Rodrigo ;
Guerrero-Santos, Ramiro .
MOLECULAR CATALYSIS, 2019, 464 :63-73
[36]   Palladium nanoparticles embedded on thiourea-modified chitosan: a green and sustainable heterogeneous catalyst for the Suzuki reaction in water [J].
Affrose, Abdullah ;
Suresh, Palaniswamy ;
Azath, Ismail Abulkalam ;
Pitchumani, Kasi .
RSC ADVANCES, 2015, 5 (35) :27533-27539
[37]   Preparation of heterogeneous catalysts supported on mesoporous molecular sieves modified with various N-groups and their use in the Heck reaction [J].
Demel, Jan ;
Sujandi ;
Park, Sang-Eon ;
Cejka, Jiri ;
Stepnicka, Petr .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2009, 302 (1-2) :28-35
[38]   Novel poly(N-vinyl-2-pyrrolidone) nanocomposites containing poly(amide-imide)/aluminum oxide nanostructure hybrid as a filler [J].
Mallakpour, Shadpour ;
Khadem, Elham .
HIGH PERFORMANCE POLYMERS, 2016, 28 (01) :55-63
[39]   Improved Thermoelectric Behavior of Poly(3,4-ethylenedioxythiophene)-Poly(styrenesulfonate) Using Poly(N-vinyl-2-pyrrolidone)-coated GeO2 Nanoparticles [J].
Shiraishi, Yukihide ;
Hata, Shinichi ;
Okawauchi, Yosuke ;
Oshima, Keisuke ;
Anno, Hiroaki ;
Toshima, Naoki .
CHEMISTRY LETTERS, 2017, 46 (07) :933-936
[40]   Palladium nanoparticles supported on modified single-walled carbon nanotubes: a heterogeneous and reusable catalyst in the Ullmann-type N-arylation of imidazoles and indoles [J].
Veisi, Hojat ;
Morakabati, Nekoo .
NEW JOURNAL OF CHEMISTRY, 2015, 39 (04) :2901-2907
12345