trans-diaquabis(hexafluoroacetylacetonato-O,O')manganese(II) monohydrate

被引：5
作者：
Dickman, MH
机构：
[1] Department of Chemistry, Georgetown University, Washington
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1997年 / 53卷
关键词：
D O I：
10.1107/S010827019601459X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the crystals of trans-diaquabis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')manganese(ll) monohydrate, [Mn(C5HF6O2)(2)(H2O)(2)].H2O, the Mn atom and all three water molecules lie on a crystallographic mirror plane. Two of the water molecules are coordinated to the Mn atom in a trans geometry and the third links the structure into hydrogen-bonded sheets. The two planar hexafluoroacetylacetonato ligands related by the mirror plane form a dihedral angle of 41.6(2)degrees with one another. One CF3 group displayed significant disorder.
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页码：402 / 404
页数：3
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