sp3-Linked Amorphous Carbon with Sulfonic Acid Groups as a Heterogeneous Acid Catalyst

被引：58

作者：

Suganuma, Satoshi ^{[1
]}

Nakajima, Kiyotaka ^{[1
]}

Kitano, Masaaki ^{[1
]}

Hayashi, Shigenobu ^{[2
]}

Hara, Michikazu ^{[1
]}

机构：

[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan

[2] Natl Inst Adv Ind Sci & Technol, Res Inst Instrumentat Frontier, Tsukuba, Ibaraki 305856, Japan

来源：

CHEMSUSCHEM | 2012年 / 5卷 / 09期

基金：

日本学术振兴会;

关键词：

amorphous materials; carbon; green chemistry; heterogeneous catalysis; spectroscopy; BEARING SO3H; TRIMETHYLPHOSPHINE OXIDE; OH GROUPS; P-31; NMR; ZEOLITES; SITES; HYDROLYSIS; CELLULOSE; COOH;

D O I：

10.1002/cssc.201200010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

SO3H-bearing amorphous carbon prepared from polyvinyl chloride (PVC) is studied as a heterogeneous Bronsted acid catalyst. Sulfonation of partially carbonized PVC produces amorphous carbon consisting of small SO3H-bearing carbon sheets linked by sp3-based aliphatic hydrocarbons. This carbon material exhibits much higher catalytic performance in the hydrolysis of cellobiose than conventional heterogeneous Bronsted acid catalysts with SO3H groups, including SO3H-bearing amorphous carbon derived from cellulose. This can be attributed to a high density of SO3H groups and the fast diffusion of reactants and products enabled by a flexible carbon network.

引用

页码：1841 / 1846

页数：6