Highlights of Photochemical Reactions in Microflow Reactors

被引：173

作者：

Oelgemoeller, Michael ^{[1
]}

机构：

[1] James Cook Univ, Sch Pharm & Mol Sci, Townsville, Qld 4811, Australia

来源：

CHEMICAL ENGINEERING & TECHNOLOGY | 2012年 / 35卷 / 07期

基金：

爱尔兰科学基金会;

关键词：

Microflow; Microreactor; Photochemistry; GAS-LIQUID REACTIONS; PHOTOSENSITIZED ADDITION; GREEN PHOTOCHEMISTRY; SINGLET OXYGEN; N-ALKYLATION; PHOTOCYCLOADDITION; MICROREACTOR; ISOPROPANOL; FURANONES; INTERMEDIATE;

D O I：

10.1002/ceat.201200009

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

This review highlights selected examples of photochemical transformations in microflow reactors. The main advantages of microflow reactors over conventional batch systems are superior light penetrations, controlled reaction times, precise temperature control and removal of photoproducts from the irradiated area. These features typically result in higher conversions or yields, improved selectivity, enhanced energy efficiencies and reductions of solvent volumes and consequently waste. Different types of homogeneous and heterogeneous reactions are presented, showing the superiority of microflow photochemistry over batch processes.

引用

页码：1144 / 1152

页数：9

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