Green Synthesis of H3O40PW12@MIL-100(Fe): Enhanced and Selective Adsorption of Methylene Blue from Aqueous Solution

被引:4
作者
Xia, Yue [1 ]
Tsai, Fang-Chang [1 ]
Ma, Ning [1 ]
Zhang, Ke-Deng [1 ]
Liu, Huan-Li [1 ]
Jiang, Tao [1 ]
Chiang, Tai-Chin [2 ]
机构
[1] Hubei Univ, Key Lab Green Preparat & Applicat Funct Mat, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Hubei Key Lab Polymer Mat,Sch Mat Sci & Engn,Mini, Wuhan 430062, Hubei, Peoples R China
[2] Natl Taiwan Univ Sci & Technol, Dept Mat Sci & Engn, Taipei 10607, Taiwan
关键词
Metal-Organic Framework; Polyoxometalate; Adsorption; Methylene Blue; Wastewater Treatment; METAL-ORGANIC FRAMEWORKS; WASTE-WATER; DYE REMOVAL; MIL-100(FE); MOFS; POLYOXOMETALATE; ACETALIZATION; SORPTION; ACID; IRON;
D O I
10.1166/sam.2018.3220
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A neoteric metal-organic framework (MOF) based hybrid adsorbent, 12-tungstophosphoric acid (H3O40PW12) embedded MIL-100(Fe) (iron(III) trimesate) denoted as H3O40PW12@MIL-100(Fe), was successfully synthesized by a green strategy (low temperature (<95 degrees C) and atmospheric pressure). The structure of H3O40PW12@MIL-100(Fe) was characterized by X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray spectroscopy (EDX) and N-2 adsorption. H3O40PW12@MIL100(Fe) was capable of separating cationic organic molecule methylene blue (MB) from aqueous system and proved to exhibit a higher adsorption and selectivity of MB than pure MIL-100(Fe). The adsorption was favorable at an alkaline condition and the progress obeyed the pseudo-second-order kinetic model. The results identified that this green strategy was a promising strategy to produce MOF based adsorbents with excellent adsorption performance for effective removal of toxic chemicals from waste water.
引用
收藏
页码:172 / 180
页数:9
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