Influence of oil polarity and material combination on the tribological response of greases formulated with biodegradable oils and bentonite and highly dispersed silica acid

被引:7
作者
Fiedler, M. [1 ]
Sanchez, R. [2 ]
Kuhn, E. [1 ]
Franco, J. M. [2 ]
机构
[1] Hamburg Univ Appl Sci, Lab Machine Elements & Tribol, Dept Mech Engn & Prod, D-20099 Hamburg, Germany
[2] Univ Huelva, Fac Ciencias Expt, Complex Fluid Engn Lab, Dept Ingn Quim, Huelva, Spain
关键词
biodegradable greases; base oil polarity; AFM; sliding wear; micro-scale abrasion; LUBRICATING GREASES; THICKENER AGENTS; CASTOR-OIL; DERIVATIVES; INTERFACES; CHROMATOGRAPHY; SURFACE; FORCES; FATS;
D O I
10.1002/ls.1207
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Different biodegradable lubricating greases formulated with esters of fatty acids, as base oils, and bentonite and highly dispersed silica acid, as thickener agents, were tribologically investigated in a nanotribometer and compared with polyalpha olefin greases with equal thickeners. Material combinations of steel ball on steel disc and sapphire ball on steel disc were used with different normal loads. Several friction and wear effects were found depending on the thickener and the base oil. The influence of grease components is also different in both material combinations evaluated. On the one hand, the base oil exerts a much higher impact on friction and wear in grease systems thickened with highly dispersed silica acid than in those thickened with bentonite. On the other hand, the latter reacts more sensitively to a change in material combination. Results were discussed and explained on the basis of polarity influences of the base oils and solid surfaces. Copyright (c) 2012 John Wiley & Sons, Ltd.
引用
收藏
页码:397 / 412
页数:16
相关论文
共 36 条
  • [1] Ecotribology: Environmentally acceptable tribological practices
    Bartz, WJ
    [J]. TRIBOLOGY INTERNATIONAL, 2006, 39 (08) : 728 - 733
  • [2] The biodegradability and microbial toxicity testing of lubricants - some recommendations
    Battersby, NS
    [J]. CHEMOSPHERE, 2000, 41 (07) : 1011 - 1027
  • [3] Becker G, 1988, KUNSTSTOFF HDB DUROP
  • [4] Modified smectitic Tunisian clays used in the formulation of high performance lubricating greases
    Chtourou, Manef
    Frikha, Mohamed Hedi
    Trabelsi, Mahmoud
    [J]. APPLIED CLAY SCIENCE, 2006, 32 (3-4) : 210 - 216
  • [5] Czichos H., 2010, Tribologie-Handbuch
  • [6] Determination of polar compounds, polymerized and oxidized triacylglycerols, and diacylglycerols in oils and fats - Results of collaborative studies and the standardized method (Technical Report)
    Dobarganes, MC
    Velasco, J
    Dieffenbacher, A
    [J]. PURE AND APPLIED CHEMISTRY, 2000, 72 (08) : 1563 - 1575
  • [7] Dresel WH., 1994, IND CROP PROD, V2, P281, DOI 10.1016/0926-6690(94)90119-8
  • [8] Assessment of oil polarity: Comparison of evaluation methods
    El-Mahrab-Roberta, M.
    Rosilio, V.
    Bolzinger, M. -A.
    Chaminade, P.
    Grossiord, J. -L.
    [J]. INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2008, 348 (1-2) : 89 - 94
  • [9] Tribological Properties of Greases Based on Biogenic Base Oils and Traditional Thickeners in Sapphire-Steel Contact
    Fiedler, Martin
    Kuhn, Erik
    Maria Franco, Jose
    Litters, Thomas
    [J]. TRIBOLOGY LETTERS, 2011, 44 (03) : 293 - 304
  • [10] Fleischer G., 1980, VerschleiSS und Zuverlassigkeit