Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates

被引：4

作者：

Zavakhina, M. S. ^{[1
]}

Samsonenko, D. G. ^{[1
,2
]}

Dybtsev, D. N. ^{[1
,2
]}

Yutkin, M. P. ^{[1
]}

Virovets, A. V. ^{[1
]}

Fedin, V. P. ^{[1
,2
]}

机构：

[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 03期

基金：

俄罗斯基础研究基金会;

关键词：

coordination polymers; chiral complexes; saccharic acid; magnesium complexes; copper(II) complexes; cobalt(II) complexes; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; POROSITY; SORPTION;

D O I：

10.1007/s11172-013-0098-x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral metal-organic coordination polymers [Co-2(sacch)(2)]center dot 1/2H2O center dot CH3OH (1), [Cu(sacch)(H2O)(2)]center dot 3H(2)O (2), and [Mg(H2O)(3)(sacch)] (3) (H(2)sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis.

引用

页码：716 / 721

页数：6

共 50 条

[1] Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates
M. S. Zavakhina
D. G. Samsonenko
D. N. Dybtsev
M. P. Yutkin
A. V. Virovets
V. P. Fedin
Russian Chemical Bulletin, 2013, 62 : 716 - 721
[2] Synthesis, Crystal Structure, and Electron Paramagnetic Resonance Investigations of Heteronuclear CoII/ZnII and CoII/CdII Coordination Polymers
Laessig, Daniel
Lincke, Joerg
Griebel, Jan
Kirmse, Reinhard
Krautscheid, Harald
INORGANIC CHEMISTRY, 2011, 50 (01) : 213 - 219
[3] Structural Versatility of 3d-CeIII Heterometallic Coordination Polymers Using CoII or CuII
Cruz, Carlos
Spodine, Evgenia
Audebrand, Nathalie
Venegas-Yazigi, Diego
Paredes-Garcia, Veronica
CRYSTAL GROWTH & DESIGN, 2018, 18 (09) : 5155 - 5165
[4] Coordination polymers assembled from angular dipyridyl ligands and CuII, CdII, CoII salts:: Crystal structures and properties
Huang, Z
Song, HB
Du, M
Chen, ST
Bu, XH
Ribas, J
INORGANIC CHEMISTRY, 2004, 43 (03) : 931 - 944
[5] MnII, CuII and CoII coordination polymers showing antiferromagnetism, and the coexistence of spin frustration and long range magnetic ordering
Li, Ya-Min
Xiao, Chang-Yu
Zhang, Xu-Dong
Xu, Yan-Qing
Lun, Hui-Jie
Niu, Jing-Yang
CRYSTENGCOMM, 2013, 15 (38) : 7756 - 7762
[6] Arylhydrazones of barbituric acid: synthesis, coordination ability and catalytic activity of their CoII, CoII/III and CuII complexes toward peroxidative oxidation of alkanes
Palmucci, Jessica
Mahmudov, Kamran T.
Fatima, M.
Guedes da Silva, C.
Martins, Luisa M. D. R. S.
Marchetti, Fabio
Pettinari, Claudio
Pombeiro, Armando J. L.
RSC ADVANCES, 2015, 5 (102): : 84142 - 84152
[7] Control of Structure Dimensionality and Functional Studies of Flexible CuII Coordination Polymers
Ghosh, Sujit K.
Azhakar, Ramachandan
Kitagawa, Susumu
CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (06) : 870 - 875
[8] Synthesis of chiral coordination polymers by spontaneous resolution
Li, Feng
Li, Taohai
Li, Xiaoju
Li, Xing
Wang, Yuling
Cao, Rong
CRYSTAL GROWTH & DESIGN, 2006, 6 (06) : 1458 - 1462
[9] Synthesis, structure and application of chiral copper(II) coordination polymers for asymmetric acylation
Jammi, Suribabu
Rout, Laxmidhar
Saha, Prasenjit
Akkilagunta, Vijay K.
Sanyasi, Sridhar
Punniyamurthy, Tharmalingarn
INORGANIC CHEMISTRY, 2008, 47 (12) : 5093 - 5098
[10] Synthesis and crystal structures of mononuclear CuII/CoII coordination complexes from pyrazole-dicarboxylate acid derivatives
Radi, Smaail
Yahyi, Abderrahmane
Ettouhami, Abdelkader
Jha, Ambika Chaudhary
Adarsh, N. N.
Robeyns, Koen
Garcia, Yann
POLYHEDRON, 2015, 85 : 383 - 388

← 1 2 3 4 5 →