Electrochromic lutetium phthalocyanine films for in situ detection of NADH

被引：15

作者：

Basova, Tamara ^{[1
]}

Gurek, Ayse Gul ^{[2
]}

Ahsen, Vefa ^{[2
]}

Ray, Asim ^{[3
]}

机构：

[1] Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[2] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey

[3] Brunel Univ, Wolfson Ctr Mat Proc, Uxbridge UB8 3PH, Middx, England

来源：

OPTICAL MATERIALS | 2013年 / 35卷 / 03期

关键词：

Bisphthalocyanines; Electrochromic properties; Chemical sensors; NICOTINAMIDE ADENINE-DINUCLEOTIDE; MAGNETIC-PROPERTIES; LIQUID;

D O I：

10.1016/j.optmat.2012.10.017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A simple and sensitive method for the detection of NADH on a glass substrate modified with spin coated electrochromic [(C6H13S)(8)Pc](2)Lu is presented. The modification of a [(C6H13S)(8)Pc](2)Lu sensing layer was achieved chemically. The functionalized layer shows an efficient activity towards the NADH at conc. as low as 1 x 10(-5) M. The in situ UV-Vis and Raman measurements were carried out to study the interaction of oxidized films with NADH. The electrochromic behaviour of [(C6H13S)(8)Pc](2)Lu thin films was examined in detail under various conditions. The spin coated films deposited on glass substrate were chemically oxidized and were found to change the colour. The oxidized films were believed to be reduced to its natural form on interaction with NADH. The colour of the film changed from green to brownish-purple after interaction with NADH. Reversible electrochromism was observed, leading reusable sensor film. The transformation of the oxidised phthalocyanine films into neutral form was monitored by both in situ UV-Vis and Raman techniques. (c) 2012 Elsevier B.V. All rights reserved.

引用

页码：634 / 637

页数：4

共 24 条

[1] Characterization and organic vapor sensing properties of Langmuir-Blodgett film using a new three oxygen-linked phthalocyanine incorporating lutetium [J].

Acikbas, Yaser ;

Evyapan, Murat ;

Ceyhan, Tanju ;

Capan, Rifat ;

Bekaroglu, Oezer .

SENSORS AND ACTUATORS B-CHEMICAL, 2009, 135 (02) :426-429

[2] Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection [J].

Basova, T. ;

Jushina, I. ;

Guerek, A. G. ;

Ahsen, V. ;

Ray, A. K. .

JOURNAL OF THE ROYAL SOCIETY INTERFACE, 2008, 5 (24) :801-806

[3] Optical investigation of thin films of liquid-crystalline lutetium bisphthalocyanine [J].

Basova, T ;

Kol'tsov, E ;

Hassan, AK ;

Nabok, A ;

Ray, AK ;

Gürek, AG ;

Ahsen, V .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2004, 15 (09) :623-628

[4] SYNTHESIS, STRUCTURE, AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF LUTETIUM(III) PHTHALOCYANINE DERIVATIVES - LUPC2.CH2CL2 AND [LUPC(OAC)(H2O)2].H2O.2CH3OH [J].

DECIAN, A ;

MOUSSAVI, M ;

FISCHER, J ;

WEISS, R .

INORGANIC CHEMISTRY, 1985, 24 (20) :3162-3167

[5] Reactivity of poly(anilineboronic acid) with NAD+ and NADH [J].

Deore, LA ;

Freund, MS .

CHEMISTRY OF MATERIALS, 2005, 17 (11) :2918-2923

[6]

Gregory P, 2000, J PORPHYR PHTHALOCYA, V4, P432, DOI 10.1002/(SICI)1099-1409(200006/07)4:4<432::AID-JPP254>3.3.CO

[7]

2-E

[8] Synthesis, structure, and spectroscopic and magnetic properties of mesomorphic octakis(hexylthio)-substituted phthalocyanine rare-earth metal sandwich complexes [J].

Gurek, AG ;

Basova, T ;

Luneau, D ;

Lebrun, C ;

Kol'tsov, E ;

Hassan, AK ;

Ahsen, V .

INORGANIC CHEMISTRY, 2006, 45 (04) :1667-1676

[9] Synthesis, structure, spectroscopic properties, and magnetic properties of an octakis(alkylthio)-substituted lutetium(III) bisphthalocyanine [J].

Gürek, AG ;

Ahsen, V ;

Luneau, D ;

Pécaut, J .

INORGANIC CHEMISTRY, 2001, 40 (18) :4793-4797

[10] BIS(2,3-NAPHTHALOCYANINATO)LUTETIUM(III) AND (2,3-NAPHTHALOCYANINATO)(PHTHALOCYANINATO)LUTETIUM(III) COMPLEXES - SYNTHESIS, SPECTROSCOPIC CHARACTERIZATION, AND ELECTROCHEMISTRY [J].

GUYON, F ;

PONDAVEN, A ;

GUENOT, P ;

LHER, M .

INORGANIC CHEMISTRY, 1994, 33 (21) :4787-4793

← 1 2 3 →