Copper-Catalyzed N-Benzoylation of Amines via Aerobic C-C Bond Cleavage

被引：42

作者：

Fan, Wenyou ^{[1
]}

Yang, Youqing ^{[1
]}

Lei, Jianhua ^{[1
]}

Jiang, Qijian ^{[1
]}

Zhou, Wang ^{[1
]}

机构：

[1] Xiangtan Univ, Coll Chem Engn, Xiangtan 411105, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 80卷 / 17期

基金：

美国国家科学基金会;

关键词：

CARBON-CARBON BOND; AMIDE SYNTHESIS; OXIDATIVE CLEAVAGE; DIRECT AMIDATION; KETONES; ALDEHYDES; EFFICIENT; ALCOHOLS; OXYGENATION; ACTIVATION;

D O I：

10.1021/acs.joc.5b01670

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general copper/air catalytic system for selectively oxidative C-C bond cleavage of 1,2-diarylethan-1-one has been developed, giving aromatic aldehydes and N-benzoylation products of various amines in moderate to excellent yields. This research provides an alternative approach for the N-benzoylation of amine in mild and neutral conditions.

引用

页码：8782 / 8789

页数：8

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