[N(n-Bu)4]2[Pu(NO3)6] and [N(n-Bu)4]2[PuCl6]: Starting Materials To Facilitate Nonaqueous Plutonium(IV) Chemistry

被引：33

作者：

Reilly, Sean D. ^{[1
]}

Scott, Brian L. ^{[2
]}

Gaunt, Andrew J. ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

[2] Los Alamos Natl Lab, Mat Phys & Applicat Div, Los Alamos, NM 87545 USA

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 17期

关键词：

COMPLEXES; NP; TH; PU;

D O I：

10.1021/ic301518g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of plutonium(IV) in aqueous nitric acid with tetra-n-butylammonium nitrate leads to the immediate precipitation of [N(n-Bu)(4)](2)[Pu(NO3)(6)] (1) in high yield. The analogous reaction in HCl with tetra-n-butylammonium chloride gives [N(n-Bu)(4)](3)[PuCl6] (2). Both 1 and 2 are soluble in a range of organic solvents and have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and solid- and solution-phase vis-near-IR spectroscopy. 1 and 2 provide facile synthetic entry routes to study plutonium(IV) ligand complexation reactions in organic solvent media under both air/moisture-stable and -sensitive conditions.

引用

页码：9165 / 9167

页数：3

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