A short and efficient synthesis of ketene O,O- and S,S-acetals under focused microwave irradiation and solvent-free conditions

被引：24

作者：

DiazOrtiz, A ^{[1
]}

Prieto, P ^{[1
]}

Loupy, A ^{[1
]}

Abenhaim, D ^{[1
]}

机构：

[1] UNIV PARIS 11,LAB REACT SELECT SUPPORTS,CNRS UA 478,F-91405 ORSAY,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期

关键词：

D O I：

10.1016/0040-4039(96)00110-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new methodology leading to ketene O,O- and S,S-acetals is reported. The title compounds were prepared from the corresponding halogenated precursors under microwave irradiation in the absence of solvent within 5-25 minutes with excellent yields. Yields obtained under microwaves are by far the best when compared to those obtained by ultrasound or classical heating in the same conditions of time and temperature.

引用

页码：1695 / 1698

页数：4

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