Synthesis and X-ray Structural Characterization of the Polymeric Cluster Compound [Hg3(O2SePh)(SePh)5]n

被引：4
作者：
Stieler, Rafael [1 ,2 ]
Back, Davi F. [1 ]
Tirloni, Barbara [1 ]
Burrow, Robert A. [1 ]
Lang, Ernesto S. [1 ]
机构：
[1] Univ Fed Santa Maria, Dept Quim, BR-97119900 Santa Maria, RS, Brazil
[2] Univ Fed Fronteira, BR-85770000 Realeza, PR, Brazil
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 10期
关键词：
Polymeric cluster compound; Phenyl-seleninic acid; Mercury; Selenium; MERCURY BIS(PHENYLSELENOLATE); CHALCOGENIDE CLUSTERS; NANOCLUSTERS; FEATURES; CADMIUM; COMPLEXES; CRYSTAL; PHENYL; LIGAND; PH;
D O I：
10.1002/zaac.201200257
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two synthetic routes to prepare [Hg3(O2SePh)(SePh)5]n and its structural characterization are presented in this paper. This compound results either from the partial oxidation of mercury phenylselenolate clusters or from a mixture of its components with defined stoichiometry. This compound was observed in almost all of our reactions as a by-product, during the development of the synthesis of new mercury selenolate clusters. It was now characterized by single-crystal X-ray diffractometry, elemental analysis, and infrared spectroscopy.
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页码：1501 / 1503
页数：3
相关论文
共 29 条
  • [1] Mercury bis(phenyltellurolate) as a precursor for the synthesis of binary and ternary nanoclusters
    Back, Davi F.
    de Oliveira, Gelson N. M.
    Burrow, Robert A.
    Castellano, Ernesto E.
    Abram, Ulrich
    Lang, Ernesto S.
    [J]. INORGANIC CHEMISTRY, 2007, 46 (07) : 2356 - 2358
  • [2] Back T. G., 2011, SELENIUM ORGANOSELEN, DOI [10.1002/9781119951438.eibc0198, DOI 10.1002/9781119951438.EIBC0198]
  • [3] Synthesis and crystal structure of [Cd10Se4(SePh)12(PPh3)4] and [Cd16(SePh)32(PPh3)2]
    Behrens, S
    Bettenhausen, M
    Eichhöfer, A
    Fenske, D
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (24) : 2797 - 2799
  • [4] Cadmium nanoclusters with phenylselenolato- and phenyltellurolato ligands: Synthesis and structural characterization of [Cd17Se4(SePh)(24)(PPh3)(4)][Cd8Se(SePh)(12)Cl-4], [Cd(DMF)(6)][Cd8Se(SePh)(12)Cl-4], [Cd8Se(SePh)(14)(PPh3)(2)], [Cd8Se(SePh)(14)(DMF)(3)] and [Cd8Te(TePh)(14)(PEt3)(3)]
    Behrens, S
    Fenske, D
    [J]. BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1997, 101 (11): : 1588 - 1592
  • [5] Dealing with 1,3-bis(4-nitrophenyl)triazene as intermediary ligand in the synthesis of polymeric (μ-Se)Hg-clusters:: One-pot synthetic procedures and X-ray structural characterization of [(PhSe)7Hg4BrPy]n
    Casagrande, Gleison Antonio
    Lang, Ernesto Schulz
    de Oliveira, Gelson Manzoni
    Horner, Manfredo
    Broch, Fernanda
    [J]. INORGANICA CHIMICA ACTA, 2007, 360 (05) : 1776 - 1779
  • [6] Metal Chalcogenide Clusters on the Border between Molecules and Materials
    Corrigan, John F.
    Fuhr, Olaf
    Fenske, Dieter
    [J]. ADVANCED MATERIALS, 2009, 21 (18) : 1867 - 1871
  • [7] Controlled synthesis of ternary II-II′-VI nanoclusters and the effects of metal ion distribution on their spectral properties
    DeGroot, MW
    Taylor, NJ
    Corrigan, JF
    [J]. INORGANIC CHEMISTRY, 2005, 44 (15) : 5447 - 5458
  • [8] Eichhöfer A, 2003, EUR J INORG CHEM, P1307
  • [9] Eichhöfer A, 2002, Z ANORG ALLG CHEM, V628, P2415, DOI 10.1002/1521-3749(200211)628:11<2415::AID-ZAAC2415>3.0.CO
  • [10] 2-W
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